Formation of paramagnetic adsorbed molecules on thermally activated magnesium and calcium oxides. Further studies of carbon monoxide

1983 ◽  
Vol 105 (9) ◽  
pp. 2633-2639 ◽  
Author(s):  
Russell M. Morris ◽  
Kenneth J. Klabunde
2018 ◽  
Vol 60 (7) ◽  
pp. 1416 ◽  
Author(s):  
М.А. Митцев ◽  
М.В. Кузьмин

AbstractThe adsorption of CO molecules onto ytterbium nanofilms with their thickness varying from 1 to 16 monolayers is studied. The dependences of the number of adsorbed CO molecules (adsorption isotherms) and the work function of ytterbium films on the dose of carbon monoxide are examined. It is demonstrated that both the number of adsorbed molecules and the work function depend (under equal conditions) on the nanofilm thickness; in other words, a size effect is revealed. It is found that this size effect is induced by the electrostatic interaction between the conduction electrons of ytterbium and the electrons localized on the nanofilm surface, which establish bonding between the surface and CO molecules. This interaction depends on the film thickness and limits the number of CO molecules that may be adsorbed onto the surface of a film with a given thickness.


2000 ◽  
Vol 12 (4) ◽  
pp. 354-357
Author(s):  
David R Smart ◽  
Paul D Mark

2000 ◽  
Vol 80 (12) ◽  
pp. 2813-2825
Author(s):  
O. N. Senkov, J. J. Jonas, F. H. Froes
Keyword(s):  

Sign in / Sign up

Export Citation Format

Share Document