Solvation of hydrogen ions in mixed water-alcohol ion clusters

1983 ◽  
Vol 105 (7) ◽  
pp. 1814-1819 ◽  
Author(s):  
A. J. Stace ◽  
C. Moore
Keyword(s):  
Hydrogen Ions ◽  
Ion Clusters ◽  
Mixed Water ◽  
Water Alcohol

Activity Coefficients of Tris(ethylenediamine)cobalt(III) Hexacyanoferrate(III) in Water and Mixed Water-Alcohol Solvents

1993 ◽  
Vol 58 (8) ◽  
pp. 1791-1797 ◽  
Author(s):  
Vladislav Holba
Keyword(s):  
Aqueous Solution ◽  
Activity Coefficients ◽  
Transfer Functions ◽  
Butyl Alcohol ◽  
Alcohol Solvents ◽  
Mixed Water ◽  
Mean Activity Coefficients ◽  
Water Alcohol

The solubility of tris(ethylenediamine)cobalt(III) hexacyanoferrate(III) were measured in aqueous solution of NaClO4, NaCl, KCl, KBr, K2SO4, Mg2SO4, (CH3)4NBr, (C2H5)4NBr, (1-C3H7)4NBr, and (1-C4H9)4NBr, as well as in the solution of NaClO4 in mixtures of water with methanol and tert-butyl alcohol. The experimental mean activity coefficients are compared with theoretical ones evaluated with the aid of extended Debye-Huckel relation. From the solubilities in water and in water-alcoholic solvents the thermodynamic transfer functions of the saturating salt were calculated.

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