The distance dependence of electron transfer reactions: rate maxima and rapid rates at large reactant separations

1984 ◽  
Vol 106 (22) ◽  
pp. 6858-6859 ◽  
Author(s):  
Bruce S. Brunschwig ◽  
Stanton Ehrenson ◽  
Norman Sutin
Keyword(s):  
Electron Transfer ◽  
Transfer Reactions ◽  
Electron Transfer Reactions ◽  
Distance Dependence

Optical transient absorption experiments reveal the failure of formal kinetics in diffusion assisted electron transfer reactions

2018 ◽  
Vol 20 (39) ◽  
pp. 25531-25546 ◽  
Author(s):  
Gonzalo Angulo ◽  
Arnulf Rosspeintner ◽  
Bernhard Lang ◽  
Eric Vauthey
Keyword(s):  
Electron Transfer ◽  
Charge Separation ◽  
Transient Absorption ◽  
Transfer Reactions ◽  
Electron Transfer Reactions ◽  
Formal Kinetics ◽  
Distance Dependence ◽  
Optical Transient

The charge separation yield is shown to be strongly influenced by the distance dependence of the reactivity, viscosity and concentration and cannot be disentangled from the preceding events.

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