Formation and reactivity of the iron carboxylic acid anion Fe(CO)4COOH- in the gas phase. Implications for the iron pentacarbonyl-catalyzed water-gas shift reaction

1984 ◽  
Vol 106 (20) ◽  
pp. 5767-5772 ◽  
Author(s):  
Kelley R. Lane ◽  
Robert E. Lee ◽  
Larry Sallans ◽  
Robert R. Squires
Keyword(s):  
Carboxylic Acid ◽  
Gas Phase ◽  
Iron Pentacarbonyl ◽  
Water Gas Shift ◽  
Water Gas Shift Reaction ◽  
Acid Anion ◽  
Carboxylic Acid Anion ◽  
Shift Reaction ◽  
Water Gas

Direct Pathway for Water–Gas Shift Reaction in Gas Phase

2014 ◽  
Vol 43 (2) ◽  
pp. 193-195 ◽  
Author(s):  
Yu Harabuchi ◽  
Satoshi Maeda ◽  
Tetsuya Taketsugu ◽  
Koichi Ohno
Keyword(s):  
Gas Phase ◽  
Water Gas Shift ◽  
Water Gas Shift Reaction ◽  
Direct Pathway ◽  
Shift Reaction ◽  
Water Gas

Effect of Water Vapour on the Equilibrium Between CaO and COS in Coal Gas

1999 ◽  
Vol 64 (1) ◽  
pp. 157-167 ◽  
Author(s):  
Miloslav Hartman ◽  
Karel Svoboda ◽  
Otakar Trnka
Keyword(s):  
Phase Composition ◽  
Gas Phase ◽  
Water Vapour ◽  
Carbonyl Sulfide ◽  
Water Gas Shift ◽  
Calcium Sulfide ◽  
Water Gas Shift Reaction ◽  
Coal Gas ◽  
Shift Reaction ◽  
Water Gas

The effectiveness of calcium oxide in the removal of carbonyl sulfide from coal gas is estimated by thermochemical computations. It is assumed that the gas phase composition is determined by the equilibria of the reactions of water vapour with calcium sulfide and carbonyl sulfide and by the water-gas-shift reaction. The proposed relationships can be employed in engineering considerations and calculations.

Sign in / Sign up

Export Citation Format

Share Document