Carbon monoxide insertion into the iron-carbon .sigma. bond in optically active CpFe(CO)(L)R. Solvent dependence and acid catalysis

1984 ◽  
Vol 106 (10) ◽  
pp. 2853-2860 ◽  
Author(s):  
Thomas C. Flood ◽  
Kent D. Campbell
Keyword(s):  
Carbon Monoxide ◽  
Acid Catalysis ◽  
Optically Active ◽  
Solvent Dependence ◽  
Sigma Bond

Carbon monoxide insertion into the iron-carbon .sigma.-bond in optically active CpFe(CO)(L)R. Preparations and optical assay

1983 ◽  
Vol 2 (11) ◽  
pp. 1590-1595 ◽  
Author(s):  
Thomas C. Flood ◽  
Kent D. Campbell ◽  
Hartley H. Downs ◽  
Saburo Nakanishi
Keyword(s):  
Carbon Monoxide ◽  
Optically Active ◽  
Optical Assay ◽  
Sigma Bond

Palladium-catalyzed alternating copolymerization of carbon monoxide with olefins bearing carbamate and amide functionalities

2001 ◽  
Vol 79 (5-6) ◽  
pp. 587-592 ◽  
Author(s):  
Christophe Moineau ◽  
Giuseppe Mele ◽  
Howard Alper
Keyword(s):  
Carbon Monoxide ◽  
Optically Active ◽  
New Class ◽  
Palladium Catalyzed ◽  
Alternating Copolymerization

The copolymerization of carbon monoxide with different olefins bearing carbamate and amide functionalities was effected using [Pd(CH3CN)4](BF4)2 as the catalyst and (R,R)-Me-DUPHOS (2:1 (v/v) MeNO2–MeOH or CH2Cl2 as the solvent). The products constitute a new class of functionalized copolymers, and were found to be optically active with a mixture of 1,4-ketone and spiroketal repeating units in the backbone. The influence of different parameters on the copolymerization of methyl N-(3-butenyl)carbamate with carbon monoxide was examined.Key words: copolymerization, carbon monoxide, olefins bearing carbamate and amide functionalities.

Copolymerization of 7-Methylenebicyclo[4.1.0]heptane with Carbon Monoxide Initiated by Optically Active Palladium Complexes

2006 ◽  
Vol 89 (8) ◽  
pp. 1574-1588 ◽  
Author(s):  
Daisuke Takeuchi ◽  
Ayami Yasuda ◽  
Takeshi Okada ◽  
Junpei Kuwabara ◽  
Kohtaro Osakada ◽  
...  
Keyword(s):  
Carbon Monoxide ◽  
Palladium Complexes ◽  
Optically Active

The N-benzoyl isocyanide group: A .pi.-acceptor ligand similar to carbon monoxide and a new route to optically active chromium(0) complexes

1979 ◽  
Vol 18 (11) ◽  
pp. 3167-3170 ◽  
Author(s):  
G. Simonneaux ◽  
P. Le Maux ◽  
G. Jaouen ◽  
R. Dabard
Keyword(s):  
Carbon Monoxide ◽  
Optically Active ◽  
Group A
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