Synthesis and x-ray crystal structure of the first transition-metal cluster involving framework phosphorus-phosphorus double bonds

1984 ◽  
Vol 106 (5) ◽  
pp. 1495-1496 ◽  
Author(s):  
Marilyn M. Olmstead ◽  
Philip P. Power
Keyword(s):  
Crystal Structure ◽  
Transition Metal ◽  
Metal Cluster ◽  
Double Bonds ◽  
X Ray ◽  
Transition Metal Cluster

scholarly journals Synthesis and Crystal Structure of a Novel Octahedral Fe4Cr2 Transition Metal Cluster Complex Cp2Cr2Fe4(CO)12(μ6-O)

1999 ◽  
Vol 23 (6) ◽  
pp. 388-389
Author(s):  
Li-Cheng Song ◽  
Wen-Qi Gao ◽  
Xiao-Ying Huang
Keyword(s):  
Crystal Structure ◽  
Transition Metal ◽  
Diffraction Analysis ◽  
Metal Cluster ◽  
Cluster Complex ◽  
X Ray Diffraction ◽  
Synthesis And Crystal Structure ◽  
X Ray ◽  
Transition Metal Cluster

Reaction of Cp(OC)2Cr=S = Cr(CO)2Cp with Fe3(CO)12 affords an encapsulated μ6-O octahedral Fe4Cr2 cluster complex Cp2Cr2Fe4(CO)12(μ6-O), whose crystal structure is determined by X-ray diffraction analysis.

The syntheses and X-ray crystal structures of novel transition metal cluster arrays containing 2–5 coordinated [(CO)9Co3(μ3-CCOO)]− ligands in a variety of geometries

Polyhedron ◽  
1999 ◽  
Vol 18 (13) ◽  
pp. 1869-1880 ◽  
Author(s):  
Victor Calvo-Perez ◽  
Maoyu Shang ◽  
Glenn P.A Yap ◽  
Arnold L Rheingold ◽  
Thomas P Fehlner
Keyword(s):  
Transition Metal ◽  
Crystal Structures ◽  
Metal Cluster ◽  
X Ray ◽  
Transition Metal Cluster

Systhesis, Characterization and Spectroscopic Properties of (2E,6E)-2,6-Bis(2,3,4-tri-methoxy-benzylidene)cyclohexanone

2011 ◽  
Vol 396-398 ◽  
pp. 2338-2341
Author(s):  
Xing Chuan Wei ◽  
Zhi Li Liu ◽  
Kun Zhang ◽  
Zhi Yun Du ◽  
Xi Zheng
Keyword(s):  
Crystal Structure ◽  
Acetic Acid ◽  
Hydrogen Bonds ◽  
Title Compound ◽  
Spectroscopic Properties ◽  
Spectral Studies ◽  
Double Bonds ◽  
X Ray ◽  
Π Interactions ◽  
X Ray Crystallography

In this paper, (2E,6E)-2,6-Bis(2,3,4-tri-methoxy -benzylidene)cyclohexanone (omitted as tmbcho) (1) was obtained by the reaction of acetic acid, tetrahydrofuran, cyclohexanone and 2,3,4-tri-methoxy-benzaldehyde. Three non-classic hydrogen bonds were observed in the compound. X-ray crystallography shows that the crystal structure is stabilized by intermolecular C-H•••π interactions and it contains plenty of conjugated double bonds. The title compound was characterized by UV-vis and fluorescent spectral studies.

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