Reactions of CoCp+ (Cp = cyclopentadienyl) with hydrocarbons in the gas phase. Observation of novel skeletal isomerizations/dehydrocyclizations resulting in cobaltocenium formation

1985 ◽  
Vol 107 (25) ◽  
pp. 7399-7407 ◽  
Author(s):  
D. B. Jacobson ◽  
B. S. Freiser
Keyword(s):  
1981 ◽  
Vol 22 (21) ◽  
pp. 1949-1952 ◽  
Author(s):  
Walter C. Eisenberg ◽  
Alan Snelson ◽  
James Veltman ◽  
Robert W. Murray

1979 ◽  
Vol 57 (11) ◽  
pp. 1341-1349 ◽  
Author(s):  
J. W. Bevan ◽  
B. Martineau ◽  
C. Sandorfy

First overtones of H—F and D—F stretching vibrations in hydrogen bonded complexes with dimethylether, diethylether, and acetone have been measured in the gas phase. The assignment of the observed bands is discussed together with previously made observations on the fundamentals. Anharmonicity constants of the order of −200 and −100 cm−1 are determined for the most probable assignments from the available data for the H—F and D—F stretching vibrations (ν1) while their values in the "free" H—F and D—F molecules are −90 and −46 cm−1 respectively. The spectra are compatible with a coupling constant between the ν1 and the bridge stretching vibration (ν3) of the order of +70 cm−1.


2021 ◽  
Author(s):  
Dominique Maué ◽  
Patrick Strebert ◽  
Dominic Bernhard ◽  
Sören Rösel ◽  
Peter Schreiner ◽  
...  

2005 ◽  
Vol 109 (12) ◽  
pp. 2765-2767 ◽  
Author(s):  
Vince Cammarata ◽  
Tan Guo ◽  
Andreas Illies ◽  
Lidong Li ◽  
Philip Shevlin

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