Dynamics of monoolefin-metal ion complexes in the gas phase. Determination of the number of labile .beta.-hydrogens by reaction with ethene-d4

1985 ◽  
Vol 107 (1) ◽  
pp. 72-80 ◽  
Author(s):  
D. B. Jacobson ◽  
B. S. Freiser
Keyword(s):  
Gas Phase ◽  
Metal Ion ◽  
Phase Determination ◽  
Metal Ion Complexes

Frontiers in the infrared spectroscopy of gas phase metal ion complexes

2005 ◽  
Vol 29 (12) ◽  
pp. 1495 ◽  
Author(s):  
Nicholas R. Walker ◽  
Richard S. Walters ◽  
Michael A. Duncan
Keyword(s):  
Infrared Spectroscopy ◽  
Gas Phase ◽  
Metal Ion ◽  
Metal Ion Complexes

Bond energies in two-ligand gas-phase metal-ion complexes exhibit trans influence

1982 ◽  
Vol 104 (3) ◽  
pp. 888-889 ◽  
Author(s):  
Manfred M. Kappes ◽  
Roger W. Jones ◽  
Ralph H. Staley
Keyword(s):  
Gas Phase ◽  
Metal Ion ◽  
Bond Energies ◽  
Metal Ion Complexes ◽  
Trans Influence

Potentiometric Determination of Stability Constants of Trivalent Metal Ion Complexes with Di-p-tolyl-thiovioluric Acid

1976 ◽  
Vol 31 (8) ◽  
pp. 1096-1098 ◽  
Author(s):  
Pavan Mathur ◽  
D. P. Goel ◽  
R. P. Singh
Keyword(s):  
Stability Constants ◽  
Atomic Number ◽  
Metal Ion ◽  
Formation Constants ◽  
Potentiometric Determination ◽  
Trivalent Metal ◽  
Ionic Radii ◽  
Metal Ion Complexes

The consecutive formation constants of 1:1, 2:1, 3:1 chelate species formed by the interaction of di-p-tolyl-thiovioluric acid (D-p-TOTVA) with the tripositive lanthanons and yttrium cations were determined potentiometrically at 0.1 µ (NaClO4) at 30± 1°C, in 75% aqueous dioxan.The 1:1 formation constants (log K1) for the complexes increase with the increase in the atomic number of the lanthanon (3), with a break at gadolinium.The results indicate that the ligand bonds bidentately to heavier lanthanons (smaller ionic radii). However, definite dentate character of bonding to lighter (larger ionic radii) lanthanons could not be established.

Frontiers in the Infrared Spectroscopy of Gas Phase Metal Ion Complexes

ChemInform ◽  
2006 ◽  
Vol 37 (15) ◽  
Author(s):  
Nicholas R. Walker ◽  
Richard S. Walters ◽  
Michael A. Duncan
Keyword(s):  
Infrared Spectroscopy ◽  
Gas Phase ◽  
Metal Ion ◽  
Metal Ion Complexes
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