The triplex Diels-Alder reaction of indene and cyclic dienes

1986 ◽  
Vol 108 (25) ◽  
pp. 8021-8027 ◽  
Author(s):  
Glenn C. Calhoun ◽  
Gary B. Schuster
Keyword(s):  
Alder Reaction ◽  
Diels Alder ◽  
Diels Alder Reaction ◽  
Cyclic Dienes

ChemInform Abstract: SOME NEW DIENOPHILES IN THE DIELS-ALDER REACTION WITH ACTIVE CYCLIC DIENES

1985 ◽  
Vol 16 (28) ◽  
Author(s):  
M. G. VELIEV ◽  
M. M. GUSEINOV ◽  
L. A. YANOVSKAYA ◽  
K. YA. BURSTEIN
Keyword(s):  
Alder Reaction ◽  
Diels Alder ◽  
Diels Alder Reaction ◽  
Cyclic Dienes

Copper(i)/TF-BiphamPhos catalyzed asymmetric nitroso Diels–Alder reaction

2017 ◽  
Vol 53 (10) ◽  
pp. 1657-1659 ◽  
Author(s):  
Jun Li ◽  
Hai-Yan Tao ◽  
Chun-Jiang Wang
Keyword(s):  
Alder Reaction ◽  
Diels Alder ◽  
Highly Efficient ◽  
Diels Alder Reaction ◽  
Cyclic Dienes ◽  
High Yields

A highly efficient enantioselective nitroso Diels–Alder reaction of 6-methyl-2-nitroso pyridine with various 1,3-dienes was successfully developed using a copper(i)/(S)–TF-BiphamPhos complex as the catalyst. For most of the cyclic dienes, the cycloadducts were obtained in high yields with excellent regio-, and stereoselectivities. Acyclic 2-silyloxy-1,3-diene also worked well in the reaction.

Some new dienophiles in the diels-alder reaction with active cyclic dienes

Tetrahedron ◽  
1985 ◽  
Vol 41 (4) ◽  
pp. 749-761 ◽  
Author(s):  
M.G. Veliev ◽  
M.M. Guseinov ◽  
L.A. Yanovskaya ◽  
K.Ya. Burstein
Keyword(s):  
Alder Reaction ◽  
Diels Alder ◽  
Diels Alder Reaction ◽  
Cyclic Dienes

Proton-driven diels-alder reaction of azo compounds with cyclic dienes

Tetrahedron ◽  
1986 ◽  
Vol 42 (6) ◽  
pp. 1769-1777 ◽  
Author(s):  
Stephen F. Nelsen ◽  
Silas C. Blackstock ◽  
Timothy B. Frigo
Keyword(s):  
Alder Reaction ◽  
Diels Alder ◽  
Azo Compounds ◽  
Diels Alder Reaction ◽  
Cyclic Dienes

ChemInform Abstract: DIELS-ALDER REACTION OF DIMETHYLBUTADIENYLCARBINOL WITH CYCLIC DIENES

1980 ◽  
Vol 11 (34) ◽  
Author(s):  
M. G. VELIEV ◽  
M. M. GUSEINOV ◽  
L. A. YANOVSKAYA ◽  
S. A. MAMEDOV ◽  
A. A. BAIRAMOV
Keyword(s):  
Alder Reaction ◽  
Diels Alder ◽  
Diels Alder Reaction ◽  
Cyclic Dienes

The intramolecular Diels–Alder reaction: recent advances and synthetic applications

1984 ◽  
Vol 62 (2) ◽  
pp. 183-234 ◽  
Author(s):  
Alex G. Fallis
Keyword(s):  
Natural Products ◽  
Total Synthesis ◽  
Alder Reaction ◽  
Diels Alder ◽  
Synthetic Strategy ◽  
Diels Alder Reaction ◽  
Recent Advances ◽  
Cyclic Dienes

Recent advances and examples of the intramolecular Diels–Alder reaction are summarized and applications to the total synthesis of natural products, both completed and in progress, noted. A detailed discussion of trienes leading to bicyclo[4.3.0]nonene skeletons is followed by examples of bicyclo[4.4.0]decenes and adducts arising from ortho-quinodimethane precursors. Cycloadditions affording bicyclo[n.4.0] systems and bridged-ring adducts from cyclic dienes conclude this survey which is followed by a discussion of unreactive trienes and a brief analysis of synthetic strategy to complete the review.

scholarly journals Continuous flow of nitroso Diels–Alder reaction

2015 ◽  
Vol 51 (61) ◽  
pp. 12309-12312 ◽  
Author(s):  
Erika Nakashima ◽  
Hisashi Yamamoto
Keyword(s):  
Continuous Flow ◽  
Alder Reaction ◽  
Diels Alder ◽  
Reaction Systems ◽  
Diels Alder Reaction ◽  
Temperature And Pressure ◽  
Flow Reaction ◽  
Cyclic Dienes

Our flow reaction systems have provided quantitative yields of nitroso Diels–Alder products with no byproducts in cases of cyclic dienes without temperature and pressure controls.

scholarly journals Diels-Alder Reaction of β-Fluoro-β-nitrostyrenes with Cyclic Dienes

2020 ◽  
Author(s):  
Savva A. Ponomarev ◽  
Roman V. Larkovich ◽  
Alexander S. Aldoshin ◽  
Andrey A. Tabolin ◽  
Sema L. Ioffe ◽  
...  
Keyword(s):  
Kinetic Data ◽  
Activation Parameters ◽  
Alder Reaction ◽  
Diels Alder ◽  
Diels Alder Reaction ◽  
Synthetic Utility ◽  
Cyclic Dienes

The Diels-Alder reaction of β-fluoro-β-nitrostyrenes with cyclic 1,3-dienes was investigated. A series of novel monofluorinated norbornenes was prepared in up to 97% yield. The reaction with 1,3‑cyclohexadiene permits the preparation of monofluorinated bicyclo[2.2.2]oct-2-enes. The kinetic data of the reaction with cyclopentadiene and cyclohexadiene-1,3 were used to calculate activation parameters. Furthermore, the synthetic utility of the cycloadducts obtained was demonstrated.

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