Intramolecular coordination of bidentate Lewis bases to a cofacial binuclear copper(II) complex

1986 ◽  
Vol 108 (23) ◽  
pp. 7430-7431 ◽  
Author(s):  
Andrew W. Maverick ◽  
Scott C. Buckingham ◽  
Qin. Yao ◽  
Julie R. Bradbury ◽  
George G. Stanley
Keyword(s):  
Intramolecular Coordination ◽  
Binuclear Copper ◽  
Lewis Bases

ChemInform Abstract: Intramolecular Coordination of Bidentate Lewis Bases to a Cofacial Binuclear Copper(II) Complex.

ChemInform ◽  
1987 ◽  
Vol 18 (13) ◽  
Author(s):  
A. W. MAVERICK ◽  
S. C. BUCKINGHAM ◽  
Q. YAO ◽  
J. R. BRADBURY ◽  
G. G. STANLEY
Keyword(s):  
Intramolecular Coordination ◽  
Binuclear Copper ◽  
Lewis Bases

Features of Formation of Mononuclear and Binuclear Copper(II) Complexes with 2,2'-Bipyridyl and closo-Decaborate Anion

2020 ◽  
Vol 65 (9) ◽  
pp. 1343-1350
Author(s):  
E. A. Malinina ◽  
V. V. Avdeeva ◽  
S. E. Korolenko ◽  
S. E. Nefedov ◽  
L. V. Goeva ◽  
...  
Keyword(s):  
Binuclear Copper ◽  
Closo Decaborate Anion

Cocrystals of 1,2-bis(chloromercurio) tetrafluorobenzene with netural bidentate Lewis bases

2007 ◽  
Vol 63 (a1) ◽  
pp. s166-s166
Author(s):  
M. Yu. Antipin ◽  
A. A. Yakovenko ◽  
J. H. Gallegos ◽  
T. V. Timofeeva
Keyword(s):  
Lewis Bases

scholarly journals Relativistic Effects on NMR Parameters of Halogen-Bonded Complexes

Molecules ◽  
2019 ◽  
Vol 24 (23) ◽  
pp. 4399 ◽  
Author(s):  
Ibon Alkorta ◽  
José Elguero ◽  
Manuel Yáñez ◽  
Otilia Mó ◽  
M. Merced Montero-Campillo
Keyword(s):  
Relativistic Effects ◽  
Lewis Base ◽  
Coupling Constants ◽  
Basic Site ◽  
Lewis Bases ◽  
Nmr Parameters ◽  
Quadrupolar Coupling ◽  
Binary Complexes ◽  
Computational Level ◽  
Bonded Complexes

Relativistic effects are found to be important for the estimation of NMR parameters in halogen-bonded complexes, mainly when they involve the heavier elements, iodine and astatine. A detailed study of 60 binary complexes formed between dihalogen molecules (XY with X, Y = F, Cl, Br, I and At) and four Lewis bases (NH3, H2O, PH3 and SH2) was carried out at the MP2/aug-cc-pVTZ/aug-cc-pVTZ-PP computational level to show the extent of these effects. The NMR parameters (shielding and nuclear quadrupolar coupling constants) were computed using the relativistic Hamiltonian ZORA and compared to the values obtained with a non-relativistic Hamiltonian. The results show a mixture of the importance of the relativistic corrections as both the size of the halogen atom and the proximity of this atom to the basic site of the Lewis base increase.

Molecular structures and magnetic properties of .mu.-phenolato binuclear copper(II) complexes incorporating chloro, hydroxo, and azido exogenous bridging ligands

1988 ◽  
Vol 27 (21) ◽  
pp. 3710-3716 ◽  
Author(s):  
Azdine Benzekri ◽  
Patrick Dubourdeaux ◽  
Jean Marc Latour ◽  
Jean Laugier ◽  
Paul Rey
Keyword(s):  
Magnetic Properties ◽  
Molecular Structures ◽  
Binuclear Copper ◽  
Bridging Ligands

Addition of the oxirane derivatives to CO2 catalyzed by Lewis bases under mild conditions

2021 ◽  
Vol 70 (6) ◽  
pp. 1118-1123
Author(s):  
I. S. Gabov ◽  
V. A. Kuznetsov ◽  
I. S. Puzyrev ◽  
A. V. Pestov
Keyword(s):  
Lewis Bases ◽  
Mild Conditions
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