Molecular hydrogen complexes of the transition metals. 2. Preparation, structure, and reactivity of W(CO)3(PCy3)2 and W(CO)3(P-iso-Pr3)2, .eta.2-H2 complex precursors exhibiting metal.cntdot..cntdot..cntdot.hydrogen-carbon interaction

Harvey J. Wasserman; Gregory J. Kubas; Robert R. Ryan

doi:10.1021/ja00269a027

Molecular hydrogen complexes of the transition metals. 2. Preparation, structure, and reactivity of W(CO)3(PCy3)2 and W(CO)3(P-iso-Pr3)2, .eta.2-H2 complex precursors exhibiting metal.cntdot..cntdot..cntdot.hydrogen-carbon interaction

Journal of the American Chemical Society ◽

10.1021/ja00269a027 ◽

1986 ◽

Vol 108 (9) ◽

pp. 2294-2301 ◽

Cited By ~ 70

Author(s):

Harvey J. Wasserman ◽

Gregory J. Kubas ◽

Robert R. Ryan

Keyword(s):

Transition Metals ◽

Molecular Hydrogen

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ChemInform Abstract: Molecular Hydrogen Complexes of the Transition Metals. Part 2. Evidence for a New Complex, Mo(CO)(dppe)2(H2), and for Solution Equilibrium Between Dihydrogen and Dihydride Forms, M - η2-H2↔ H - M - H, in W(CO)3(PR3)2(H2).

Chemischer Informationsdienst ◽

10.1002/chin.198629245 ◽

1986 ◽

Vol 17 (29) ◽

Author(s):

G. J. KUBAS ◽

R. R. RYAN ◽

D. A. WROBLESKI

Keyword(s):

Transition Metals ◽

Molecular Hydrogen ◽

Solution Equilibrium

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ChemInform Abstract: Molecular Hydrogen Coordination to Transition Metals

ChemInform ◽

10.1002/chin.198847344 ◽

1988 ◽

Vol 19 (47) ◽

Author(s):

G. J. KUBAS

Keyword(s):

Transition Metals ◽

Molecular Hydrogen

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Reduction of carbon dioxide by molecular hydrogen in the presence of complexes of the transition metals

Bulletin of the Academy of Sciences of the USSR Division of Chemical Science ◽

10.1007/bf00855315 ◽

1972 ◽

Vol 21 (10) ◽

pp. 2263-2264 ◽

Cited By ~ 2

Author(s):

I. S. Kolornnikov ◽

T. S. Lobeeva ◽

M. E. Vol'pin

Keyword(s):

Carbon Dioxide ◽

Transition Metals ◽

Molecular Hydrogen

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Reactivity of Transition Metals (Pd, Pt, Cu, Ag, Au) toward Molecular Hydrogen Dissociation: Extended Surfaces versus Particles Supported on TiC(001) or Small Is Not Always Better and Large Is Not Always Bad

The Journal of Physical Chemistry C ◽

10.1021/jp2024445 ◽

2011 ◽

Vol 115 (23) ◽

pp. 11666-11672 ◽

Cited By ~ 62

Author(s):

Tatiana Gomez ◽

Elizabeth Florez ◽

José A. Rodriguez ◽

Francesc Illas

Keyword(s):

Transition Metals ◽

Molecular Hydrogen ◽

Hydrogen Dissociation ◽

Extended Surfaces

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Molecular hydrogen complexes of the transition metals. 7. Kinetics and thermodynamics of the interconversion between dihydride and dihydrogen forms of W(CO)3(PR3)2H2 where R = isopropyl and cyclopentyl

Journal of the American Chemical Society ◽

10.1021/ja00166a020 ◽

1990 ◽

Vol 112 (10) ◽

pp. 3855-3860 ◽

Cited By ~ 27

Author(s):

G. Rattan K. Khalsa ◽

Gregory J. Kubas ◽

Clifford J. Unkefer ◽

Lori Stepan Van der Sluys ◽

Kimberly A. Kubat-Martin

Keyword(s):

Transition Metals ◽

Molecular Hydrogen ◽

Kinetics And Thermodynamics

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Molecular Hydrogen Coordination to Transition Metals

Comments on Inorganic Chemistry ◽

10.1080/02603598808072297 ◽

1988 ◽

Vol 7 (1) ◽

pp. 17-40 ◽

Cited By ~ 32

Author(s):

Gregory J. Kubas

Keyword(s):

Transition Metals ◽

Molecular Hydrogen

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ChemInform Abstract: Molecular Hydrogen Complexes of the Transition Metals. Part 7. Kinetics and Thermodynamics of the Interconversion Between Dihydride and Dihydrogen Forms of W(CO)3(PR3)2H2 Where R: Isopropyl and Cyclopentyl.

ChemInform ◽

10.1002/chin.199033239 ◽

1990 ◽

Vol 21 (33) ◽

Author(s):

G. R. K. KHALSA ◽

G. J. KUBAS ◽

C. J. UNKEFER ◽

L. S. VAN DER SLUYS ◽

K. A. KUBAT-MARTIN

Keyword(s):

Transition Metals ◽

Molecular Hydrogen ◽

Kinetics And Thermodynamics

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Molecular hydrogen complexes: coordination of a .sigma. bond to transition metals

Accounts of Chemical Research ◽

10.1021/ar00147a005 ◽

1988 ◽

Vol 21 (3) ◽

pp. 120-128 ◽

Cited By ~ 450

Author(s):

Gregory J. Kubas

Keyword(s):

Transition Metals ◽

Molecular Hydrogen ◽

Sigma Bond

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Molecular hydrogen diffusion overpotential and local cell hydrogen transfer processes at electrodes of palladium, palladium alloys and other transition metals, and implications for theories of hydrogen overpotential

Surface Technology ◽

10.1016/0376-4583(80)90013-8 ◽

1980 ◽

Vol 11 (1) ◽

pp. 1-16 ◽

Cited By ~ 15

Author(s):

F.A. Lewis

Keyword(s):

Transition Metals ◽

Molecular Hydrogen ◽

Hydrogen Transfer ◽

Hydrogen Diffusion ◽

Palladium Alloys ◽

Transfer Processes ◽

Local Cell ◽

Hydrogen Overpotential

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Molecular hydrogen complexes of the transition metals. 3. Evidence for a new complex, Mo(CO)(dppe)2(H2), and for solution equilibrium between dihydrogen and dihydride forms, M-.eta.2-H2 .dblarw. H-M-H, in M(CO)3(PR3)2(H2)

Journal of the American Chemical Society ◽

10.1021/ja00266a058 ◽

1986 ◽

Vol 108 (6) ◽

pp. 1339-1341 ◽

Cited By ~ 45

Author(s):

Gregory J. Kubas ◽

R. R. Ryan ◽

Debra A. Wrobleski

Keyword(s):

Transition Metals ◽

Molecular Hydrogen ◽

Solution Equilibrium

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