Complex-Induced Proximity Effects:  The Effect of Varying Directing-Group Orientation on Carbamate-Directed Lithiation Reactions

2001 ◽  
Vol 123 (2) ◽  
pp. 315-321 ◽  
Author(s):  
Kathleen M. Bertini Gross ◽  
Peter Beak
2016 ◽  
Vol 39 ◽  
Author(s):  
William O'Grady

AbstractI focus on two challenges that processing-based theories of language must confront: the need to explain why language has the particular properties that it does, and the need to explain why processing pressures are manifested in the particular way that they are. I discuss these matters with reference to two illustrative phenomena: proximity effects in word order and a constraint on contraction.


1978 ◽  
Vol 39 (C6) ◽  
pp. C6-481-C6-483 ◽  
Author(s):  
K. Scharnberg ◽  
D. Fay ◽  
N. Schopohl

1970 ◽  
Vol 12 (3) ◽  
pp. 312-328
Author(s):  
Luthfiyah Luthfiyah

The crisis of nation is caused by the crisis of inner self and moral degradations, that politic which must be oriented to safety people, but show emphasizing to individual or group orientation finally the politic, which must have service character precisely dominated and patronage character. So, it is significant to develop cognition, affection, and psicomotoric componens on a simultant scale through education. However education has antisipatoris and preparatoris characters. The identification of democaration values and provide a model through civic education will be concrete the fundamental function of education in effort to create the humanis people and shaped unresistant education to reality. So, education can cange political culture.


2019 ◽  
Author(s):  
Sandeep Pimparkar ◽  
Trisha Bhattacharya ◽  
Arun Maji ◽  
Argha Saha ◽  
Ramasamy Jayarajan ◽  
...  

The significance of site selective functionalization stands upon the superior selectivity, easy synthesis and diverse product utility. In this work we demonstrate the <i>para</i>-selective introduction of versatile nitrile moiety, enabled by detachable and reusable H-bonded auxiliary. The methodology holds its efficiency irrespective of substrate electronic bias. The conspicuous shift in the step energetics was probed by both experimental and computational mechanistic tools heralds the inception of <i>para</i>-deuteration. The synthetic impact of the methodology was highlighted with reusability of directing group and post synthetic modifications


2019 ◽  
Author(s):  
Sandeep Pimparkar ◽  
Trisha Bhattacharya ◽  
Arun Maji ◽  
Argha Saha ◽  
Ramasamy Jayarajan ◽  
...  

The significance of site selective functionalization stands upon the superior selectivity, easy synthesis and diverse product utility. In this work we demonstrate the <i>para</i>-selective introduction of versatile nitrile moiety, enabled by detachable and reusable H-bonded auxiliary. The methodology holds its efficiency irrespective of substrate electronic bias. The conspicuous shift in the step energetics was probed by both experimental and computational mechanistic tools heralds the inception of <i>para</i>-deuteration. The synthetic impact of the methodology was highlighted with reusability of directing group and post synthetic modifications


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