Kinetics of the reaction of organosilyl hydrides with carbenium ions in an inert solvent. Silicocation intermediacy. Single electron transfer versus synchronous hydride transfer

1987 ◽  
Vol 109 (25) ◽  
pp. 7776-7781 ◽  
Author(s):  
J. Chojnowski ◽  
W. Fortuniak ◽  
W. Stanczyk
Keyword(s):  
Electron Transfer ◽  
Hydride Transfer ◽  
Single Electron ◽  
Single Electron Transfer ◽  
Carbenium Ions ◽  
Inert Solvent ◽  
Kinetics Of

The Kinetics of Single-Electron Transfer from a Pyrrole Molecule to a Persulphate Ion

2013 ◽  
Vol 40 (9) ◽  
pp. 41-43 ◽  
Author(s):  
A.I. Piskareva ◽  
Yu.V. Korshak ◽  
Ya.O. Mezhuev ◽  
M.I. Shtil'man
Keyword(s):  
Electron Transfer ◽  
Single Electron ◽  
Single Electron Transfer ◽  
Kinetics Of

Insights into the mechanisms and kinetics of the hydroperoxyl radical scavenging activity of Artepillin C

2021 ◽  
Author(s):  
Houssem Boulebd ◽  
Adam Mechler ◽  
Nguyen Thi Hoa ◽  
Pham Cam Nam ◽  
Duong Tuan Quang ◽  
...  
Keyword(s):  
Electron Transfer ◽  
Radical Scavenging Activity ◽  
Radical Scavenging ◽  
Single Electron ◽  
Scavenging Activity ◽  
Single Electron Transfer ◽  
Hydroperoxyl Radical ◽  
Electron Transfer Mechanism ◽  
Artepillin C ◽  
Kinetics Of

Through the single electron transfer mechanism, Artepillin C scavenges the hydroperoxyl radical in water approximately 572 times faster than Trolox.

Reversal of Polarity by Catalytic SET Oxidation: Synthesis of Azabicyclo[m.n.o]alkanes via Chemoselective Reduction of Amidines

2021 ◽  
Author(s):  
Sundarababu Baskaran ◽  
Kirana D V ◽  
Kanak Kanti Das
Keyword(s):  
Electron Transfer ◽  
Stereoselective Synthesis ◽  
Single Electron ◽  
Single Electron Transfer ◽  
Catalytic Method ◽  
One Pot ◽  
Oxidative System ◽  
Oxidation Synthesis

A one-pot catalytic method has been developed for the stereoselective synthesis of cyclopropane-fused cyclic amidines using CuBr2/K2S2O8 as an efficient single electron transfer (SET) oxidative system. The generality of this...

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