Rhodium alkoxide complexes. Formation of an unusually strong intermolecular hydrogen bond in (PMe3)3Rh-Otol(HOtol)

1987 ◽  
Vol 109 (21) ◽  
pp. 6563-6565 ◽  
Author(s):  
Susan E. Kegley ◽  
Colin J. Schaverien ◽  
John H. Freudenberger ◽  
Robert G. Bergman ◽  
Stephen P. Nolan ◽  
...  
Keyword(s):  
Hydrogen Bond ◽  
Intermolecular Hydrogen Bond ◽  
Strong Intermolecular Hydrogen Bond

ChemInform Abstract: Rhodium Alkoxide Complexes: Formation of an Unusually Strong Intermolecular Hydrogen Bond in (PMe3)3Rh-Otol(HOtol).

ChemInform ◽  
1988 ◽  
Vol 19 (6) ◽  
Author(s):  
S. E. KEGLEY ◽  
C. J. SCHAVERIEN ◽  
J. H. FREUDENBERGER ◽  
R. G. BERGMAN ◽  
S. P. NOLAN ◽  
...  
Keyword(s):  
Hydrogen Bond ◽  
Intermolecular Hydrogen Bond ◽  
Strong Intermolecular Hydrogen Bond

Chemical NMR shifts of protons and infrared frequencies of compounds with a strong intermolecular hydrogen bond of the O?H...O type

1965 ◽  
Vol 6 (1) ◽  
pp. 138-140 ◽  
Author(s):  
N. N. Shapet'ko ◽  
D. N. Shigorin ◽  
A. P. Skoldinov ◽  
T. S. Ryabchikova ◽  
L. N. Reshetova
Keyword(s):  
Hydrogen Bond ◽  
Intermolecular Hydrogen Bond ◽  
Strong Intermolecular Hydrogen Bond ◽  
Infrared Frequencies

A novel cocrystal explosive NTO/TZTN with good comprehensive properties

RSC Advances ◽  
2015 ◽  
Vol 5 (36) ◽  
pp. 28354-28359 ◽  
Author(s):  
Jin-Ting Wu ◽  
Jian-Guo Zhang ◽  
Tong Li ◽  
Zhi-Min Li ◽  
Tong-Lai Zhang
Keyword(s):  
Crystal Structure ◽  
Hydrogen Bond ◽  
Intermolecular Hydrogen Bond ◽  
Hydrogen Bond Interaction ◽  
Strong Intermolecular Hydrogen Bond ◽  
Comprehensive Properties ◽  
Bond Interaction

A novel binary cocrystal explosive of NTO was discovered and it exhibits strong intermolecular hydrogen bond interaction in crystal structure.

Synthesis and characterization of photothermal antibacterial hydrogel with enhanced mechanical properties

2021 ◽  
Author(s):  
Shu bin Li ◽  
Xiao Wang ◽  
Jiang Zhu ◽  
Zhenyu Wang ◽  
Lu Wang
Keyword(s):  
Mechanical Properties ◽  
Hydrogen Bond ◽  
Fe3o4 Nanoparticles ◽  
Intermolecular Hydrogen Bond ◽  
Amide Bond ◽  
Synthesis And Characterization

In this work, using carboxyl-modified Fe3O4 nanoparticles as a photothermal agent, combining the chemical amide bond and intermolecular hydrogen bond crosslinking force, a photothermal hydrogel with enhanced mechanical properties was...

Configurational and conformational studies on condensation products of biogenic amines with 2,5-anhydro-D-mannose

1985 ◽  
Vol 63 (11) ◽  
pp. 2915-2921 ◽  
Author(s):  
Ian M. Piper ◽  
David B. MacLean ◽  
Romolo Faggiani ◽  
Colin J. L. Lock ◽  
Walter A. Szarek
Keyword(s):  
Hydrogen Bond ◽  
Intermolecular Hydrogen Bond ◽  
Direct Methods ◽  
Conformational Studies ◽  
X Ray ◽  
X Ray Crystallography ◽  
H Nmr ◽  
Twist Conformation ◽  
Cell Dimensions ◽  
Internal Hydrogen Bond

The products of a Pictet–Spengler condensation of tryptamine and of histamine with 2,5-anhydro-D-mannose have been studied by X-ray crystallography to establish their absolute configuration. 1(S)-(α-D-Arabinofuranosyl)-1,2,3,4-tetrahydro-β-carboline (1), C16H20N20O4, is monoclinic, P21 (No. 4), with cell dimensions a = 13.091(4), b = 5.365(1), c = 11.323(3) Å, β = 115.78(2)°, and Z = 2. 4-(α-D-Arabinofuranosyl)imidazo[4,5-c]-4,5,6,7-tetrahydropyridine (3), C11H17N3O4, is orthorhombic, P212121 (No. 19), with cell dimensions a = 8.118(2), b = 13.715(4), c = 10.963(3) Å, and Z = 4. The structures were determined by direct methods and refined to R1 = 0.0514, R2 = 0.0642 for 3210 reflections in the case of 1, and to R1 = 0.0312, R2 = 0.0335 for 1569 reflections in the case of 3. Bond lengths and angles within both molecules are normal and agree well with those observed in related structures. In 3 the base and sugar adopt a syn arrangement, which is maintained by an internal hydrogen bond between O(2′) and N(3). The sugar adopts a normal 2T3 twist conformation. The sugar has the opposite anti arrangement in the β-carboline 1 and the conformation of the sugar is unusual; it is close to an envelope conformation with O(4′) being the atom out of the plane. This conformation is caused by a strong intermolecular hydrogen bond from O(5′) in a symmetry-related molecule to O(4′). Both compounds are held together in the crystal by extensive hydrogen-bonding networks. The conformations of the compounds in solution have been investigated by 1H nmr spectroscopy, and the results obtained were compared with those obtained by X-ray crystallography for 1 and 3.

Intermolecular Hydrogen Bond Plays a Determining Role in Product Selection of Surface Confined Schiff-base Reaction

2021 ◽  
Author(s):  
Huamei Chen ◽  
Guangyuan Feng ◽  
Qiu Liang ◽  
Enbing Zhang ◽  
Yongtao Shen ◽  
...  
Keyword(s):  
Hydrogen Bond ◽  
Schiff Base ◽  
Hydrogen Bonds ◽  
Relative Abundance ◽  
Intermolecular Hydrogen Bond ◽  
Intermolecular Hydrogen Bonds ◽  
Product Selection ◽  
Selection Of

Herein, we illustrate how the cooperation of intermolecular hydrogen bonds and conformation flexibility leads to the formation of diverse complex covalent nanostructures on the surface, while the relative abundance of...

Mechanism of proton transfer in the strong OHN intermolecular hydrogen bond

RSC Advances ◽  
2011 ◽  
Vol 1 (2) ◽  
pp. 219 ◽  
Author(s):  
Irena Majerz ◽  
Matthias J. Gutmann
Keyword(s):  
Hydrogen Bond ◽  
Proton Transfer ◽  
Intermolecular Hydrogen Bond
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