Cyclometalation of 2,6-di-tert-butylphenoxide ligands by tantalum aryl groups: aliphatic carbon-hydrogen bond activation and aryl isomerization via benzyne (o-phenylene) intermediates

1987 ◽  
Vol 109 (21) ◽  
pp. 6471-6478 ◽  
Author(s):  
Linda R. Chamberlain ◽  
Judith L. Kerschner ◽  
Arlene P. Rothwell ◽  
Ian P. Rothwell ◽  
John C. Huffman
Keyword(s):  
Hydrogen Bond ◽  
Bond Activation ◽  
Carbon Hydrogen Bond Activation ◽  
Aliphatic Carbon

Cyclopalladation of N-mesitylbenzylideneamines. Aromatic versus aliphatic carbon-hydrogen bond activation

1992 ◽  
Vol 11 (4) ◽  
pp. 1536-1541 ◽  
Author(s):  
Joan Albert ◽  
Rosa Maria Ceder ◽  
Montserrat Gomez ◽  
Jaume Granell ◽  
Joaquim Sales
Keyword(s):  
Hydrogen Bond ◽  
Bond Activation ◽  
Carbon Hydrogen Bond Activation ◽  
Aliphatic Carbon

Selective aliphatic carbon–hydrogen bond activation of protected alcohol substrates by cytochrome P450 enzymes

2014 ◽  
Vol 12 (15) ◽  
pp. 2479-2488 ◽  
Author(s):  
Stephen G. Bell ◽  
Justin T. J. Spence ◽  
Shenglan Liu ◽  
Jonathan H. George ◽  
Luet-Lok Wong
Keyword(s):  
Hydrogen Bond ◽  
Cytochrome P450 ◽  
Bond Activation ◽  
Cytochrome P450 Enzymes ◽  
General Methodology ◽  
Carbon Hydrogen Bond Activation ◽  
Aliphatic Carbon

Protected cyclohexanol and cyclohex-2-enol substrates were efficiently and selectively oxidised by different P450cam mutants providing a general methodology for generating substituted diols using biocatalysts.

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