Transfer to organometallic chemistry of substituent constants from organic chemistry. 1. Resolution of longstanding anomalies in the chemistry of organocobalt B12 models and organocobalamins

1987 ◽  
Vol 109 (20) ◽  
pp. 6045-6052 ◽  
Author(s):  
Luigi G. Marzilli ◽  
Fernando Bayo ◽  
Michael F. Summers ◽  
L. Brannon Thomas ◽  
Ennio Zangrando ◽  
...  
Keyword(s):  
Organic Chemistry ◽  
Organometallic Chemistry ◽  
Substituent Constants

scholarly journals Recent Advances in Organometallic Chemistry and Catalysis

Catalysts ◽  
2021 ◽  
Vol 11 (5) ◽  
pp. 646
Author(s):  
Victorio Cadierno
Keyword(s):  
Organic Chemistry ◽  
Organometallic Chemistry ◽  
Organometallic Compounds ◽  
Synthetic Methodology ◽  
Recent Advances

The use of organometallic compounds in organic chemistry is one of the cornerstones of the modern synthetic methodology for the activation and generation of new bonds in a molecule [...]

scholarly journals Arthur John Birch. 3 August 1915 — 8 December 1995

2007 ◽  
Vol 53 ◽  
pp. 21-44 ◽  
Author(s):  
Rodney W. Rickards ◽  
John Cornforth
Keyword(s):  
Organic Chemistry ◽  
Twentieth Century ◽  
Natural Products ◽  
Organometallic Chemistry ◽  
Oral Contraceptives ◽  
Aromatic Compounds ◽  
Liquid Ammonia ◽  
Wide Range ◽  
National Science ◽  
The Subject

Arthur John Birch AC CMG FAA FRS was one of the great masters of organic chemistry of the twentieth century. His extraordinary creativity left its imprint across the breadth of the subject in its broadest sense, from synthesis to biochemistry to organometallic chemistry. He remains best known for the reaction that bears his name, the Birch reduction of aromatic compounds by solutions of sodium and ethanol in liquid ammonia. This process has wide application, most notably in the commercial synthesis of oral contraceptives, giving rise to his being called ‘the father of the pill’, although he himself preferred the more remote ‘grandfather’ relationship. His polyketide theory, which accounts for the biosynthetic origins of a wide range of natural products, is less widely acknowledged today simply because it has become absorbed into the accepted knowledge base of the subject. His final researches on the use of diene iron tricarbonyl derivatives in synthesis are equally distinguished and have prompted others to extend their application. During his career he was involved in the design of three new university chemistry buildings, one of which now bears his name, and contributed influential advice to governments on national science policies.

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