Barriers to rotation adjacent to double bonds. 3. The carbon-oxygen barrier in formic acid, methyl formate, acetic acid, and methyl acetate. The origin of ester and amide resonance

1987 ◽  
Vol 109 (20) ◽  
pp. 5935-5943 ◽  
Author(s):  
Kenneth B. Wiberg ◽  
Keith E. Laidig
Keyword(s):  
Acetic Acid ◽  
Formic Acid ◽  
Methyl Acetate ◽  
Methyl Formate ◽  
Oxygen Barrier ◽  
Double Bonds ◽  
Acid Methyl ◽  
Amide Resonance

A selected ion flow tube study of the reactions of various nitrogen containing ions with formic acid, acetic acid, and methyl formate

2005 ◽  
Vol 247 (1-3) ◽  
pp. 55-60 ◽  
Author(s):  
Douglas M. Jackson ◽  
Nathan J. Stibrich ◽  
Jason L. McLain ◽  
Lillian D. Fondren ◽  
Nigel G. Adams ◽  
...  
Keyword(s):  
Acetic Acid ◽  
Formic Acid ◽  
Methyl Formate ◽  
Flow Tube ◽  
Ion Flow ◽  
Selected Ion Flow Tube ◽  
Tube Study

Heats of vaporization of alkyl esters of formic, acetic and propionic acids

1980 ◽  
Vol 45 (12) ◽  
pp. 3233-3240 ◽  
Author(s):  
Václav Svoboda ◽  
Věra Uchytilová ◽  
Vladimír Majer ◽  
Jiří Pick
Keyword(s):  
Acetic Acid ◽  
Formic Acid ◽  
Propionic Acid ◽  
Complete Data ◽  
Methyl Ethyl ◽  
Alkyl Esters ◽  
Butyl Esters ◽  
Acid Methyl ◽  
Propyl Esters ◽  
Heats Of Vaporization

Heats of vaporization of ethyl, propyl, butyl esters of formic acid, methyl, ethyl, propyl and butyl esters of acetic acid and methyl, ethyl and propyl esters of propionic acid were measured. These measurements reassume and complete data known from the literature. From the combination of values of heats of vaporization, the cohesive and vaporization internal energies of the set investigated were computed in the dependence on temperature.

Catalytic Reduction of Acetic Acid, Methyl Acetate, and Ethyl Acetate over Silica-Supported Copper

2000 ◽  
Vol 193 (1) ◽  
pp. 16-28 ◽  
Author(s):  
M.A.Natal Santiago ◽  
M.A. Sánchez-Castillo ◽  
R.D. Cortright ◽  
J.A. Dumesic
Keyword(s):  
Acetic Acid ◽  
Ethyl Acetate ◽  
Methyl Acetate ◽  
Catalytic Reduction ◽  
Acid Methyl

FREE RADICALS BY MASS SPECTROMETRY: XV. THE: MERCURY-PHOTOSENSITIZED DECOMPOSITION OF FORMIC ACID, ACETIC ACID, AND METHYL FORMATE

1959 ◽  
Vol 37 (2) ◽  
pp. 389-402 ◽  
Author(s):  
P. Kebarle ◽  
F. P. Lossing
Keyword(s):  
Acetic Acid ◽  
Free Radicals ◽  
Formic Acid ◽  
Methyl Formate ◽  
Intramolecular Rearrangement ◽  
Significant Extent ◽  
Alternative Mode ◽  
Decomposition Reactions ◽  
Intramolecular Rearrangements ◽  
No Free Radicals

The Hg(3P1) photosensitized decomposition of formic acid proceeds by two intramolecular rearrangement reactions, leading respectively to H2O and CO, and to H2 and CO2. No free radicals are produced. The decomposition reactions of methyl formate and of acetic acid proceed predominantly by the formation of free radicals, but intramolecular rearrangements also occur to a significant extent. For both these latter compounds the evidence suggests the occurrence of two modes of dissociation into free radicals:[Formula: see text]No evidence for the alternative mode of dissociation[Formula: see text]was found.

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