Vibrational circular dichroism in transition-metal complexes. 3. Ring currents and ring conformations of amino acid ligands

1987 ◽  
Vol 109 (5) ◽  
pp. 1551-1559 ◽  
Author(s):  
Teresa B. Freedman ◽  
Daryl A. Young ◽  
M. Reza Oboodi ◽  
Laurence A. Nafie
Keyword(s):  
Circular Dichroism ◽  
Amino Acid ◽  
Transition Metal ◽  
Metal Complexes ◽  
Transition Metal Complexes ◽  
Vibrational Circular Dichroism ◽  
Ring Currents ◽  
Circular Dichroïsm ◽  
Ring Conformations

Magnetic circular dichroism spectra of transition metal complexes calculated from restricted active space wavefunctions

2019 ◽  
Vol 21 (10) ◽  
pp. 5586-5597 ◽  
Author(s):  
Yonaton N. Heit ◽  
Dumitru-Claudiu Sergentu ◽  
Jochen Autschbach
Keyword(s):  
Circular Dichroism ◽  
Transition Metal ◽  
Metal Complexes ◽  
Transition Metal Complexes ◽  
Magnetic Circular Dichroism ◽  
Open Shell ◽  
Active Space ◽  
Self Consistent Field ◽  
Circular Dichroïsm ◽  
Magnetic Circular Dichroism Spectra

Multiconfigurational restricted active space (RAS) self-consistent field (SCF) or configuration interaction (CI) approaches, augmented with a treatment of spin–orbit coupling by state interaction, were used to calculate the magnetic circular dichroism , , and/or for closed- and open-shell transition metal complexes.

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