Electron transfer via dithiaspiroalkane linkages. Nature of long-range through-bond electronic coupling in disulfoxide radical cations and bis(metal) complexes and implications for the characterization of the sulfoxide bond

1988 ◽  
Vol 110 (25) ◽  
pp. 8343-8354 ◽  
Author(s):  
Alistair P. L. Rendell ◽  
George B. Bacskay ◽  
Noel S. Hush
Keyword(s):  
Electron Transfer ◽  
Metal Complexes ◽  
Long Range ◽  
Radical Cations ◽  
Electronic Coupling

Characterization of long-range electron transfer in mixed-metal [zinc,iron] hybrid hemoglobins

Biochemistry ◽  
1987 ◽  
Vol 26 (25) ◽  
pp. 8302-8312 ◽  
Author(s):  
Jacqueline L. McGourty ◽  
Sydney E. Peterson-Kennedy ◽  
Winnie Y. Ruo ◽  
Brian M. Hoffman
Keyword(s):  
Electron Transfer ◽  
Long Range ◽  
Mixed Metal

scholarly journals Electron Transfer Mediators for Photoelectrochemical Cells Based on Cu(I) Metal Complexes

2007 ◽  
Vol 2007 ◽  
pp. 1-10 ◽  
Author(s):  
Michele Brugnati ◽  
Stefano Caramori ◽  
Silvia Cazzanti ◽  
Luca Marchini ◽  
Roberto Argazzi ◽  
...  
Keyword(s):  
Electron Transfer ◽  
Metal Complexes ◽  
Dark Current ◽  
Monochromatic Light ◽  
Photoelectrochemical Cells ◽  
Photoelectrochemical Characterization

The preparation and the photoelectrochemical characterization of a series of bipyridine and pyridyl-quinoline Cu(I) complexes, used as electron transfer mediators in regenerative photoelectrochemical cells, are reported. The best performing mediators produced maximum IPCEs of the order of 35–40%. The J-V curves recorded under monochromatic light showed that the selected Cu(I)/(II) couples generated higher Vocs and fill factors compared to an equivalentI-/I3-cell, due to a decreased dark current.

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