Specific deuterium isotope effects on the rates of electron transfer within geminate radical-ion pairs

Ian R. Gould; Samir. Farid

doi:10.1021/ja00231a053

Specific deuterium isotope effects on the rates of electron transfer within geminate radical-ion pairs

Journal of the American Chemical Society ◽

10.1021/ja00231a053 ◽

1988 ◽

Vol 110 (23) ◽

pp. 7883-7885 ◽

Cited By ~ 21

Author(s):

Ian R. Gould ◽

Samir. Farid

Keyword(s):

Electron Transfer ◽

Isotope Effects ◽

Ion Pairs ◽

Deuterium Isotope Effects

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ChemInform Abstract: Specific Deuterium Isotope Effects on the Rates of Electron Transfer within Geminate Radical-Ion Pairs.

ChemInform ◽

10.1002/chin.198909102 ◽

1989 ◽

Vol 20 (9) ◽

Author(s):

I. R. GOULD ◽

S. FARID

Keyword(s):

Electron Transfer ◽

Isotope Effects ◽

Ion Pairs ◽

Deuterium Isotope Effects

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Proton-Coupled Photoinduced Electron Transfer, Deuterium Isotope Effects, and Fluorescence Quenching in Noncovalent Benzo[a]pyrenetetraol-Nucleoside Complexes in Aqueous Solutions

Journal of the American Chemical Society ◽

10.1021/ja00122a024 ◽

1995 ◽

Vol 117 (17) ◽

pp. 4920-4929 ◽

Cited By ~ 81

Author(s):

Vladimir Ya. Shafirovich ◽

Scott H. Courtney ◽

Naiqi Ya ◽

Nicholas E. Geacintov

Keyword(s):

Electron Transfer ◽

Fluorescence Quenching ◽

Aqueous Solutions ◽

Photoinduced Electron Transfer ◽

Isotope Effects ◽

Deuterium Isotope Effects

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Ion pairs in solvolysis reactions. Kinetic deuterium isotope effects for deprotonation of carbocation intermediates in aqueous solvent

Journal of Physical Organic Chemistry ◽

10.1002/poc.610020103 ◽

1989 ◽

Vol 2 (1) ◽

pp. 15-25 ◽

Cited By ~ 6

Author(s):

Alf Thibblin

Keyword(s):

Isotope Effects ◽

Ion Pairs ◽

Aqueous Solvent ◽

Deuterium Isotope Effects

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Chemical-Substitution and Deuterium-Isotope Effects on Ultrafast Intermolecular Electron Transfer: Possible Role of Molecular Vibrations

Springer Series in Chemical Physics - Ultrafast Phenomena IX ◽

10.1007/978-3-642-85176-6_22 ◽

1994 ◽

pp. 84-85

Author(s):

Y. Nagasawa ◽

A. P. Yartsev ◽

K. Tominaga ◽

K. Yoshihara

Keyword(s):

Electron Transfer ◽

Isotope Effects ◽

Molecular Vibrations ◽

Intermolecular Electron Transfer ◽

Chemical Substitution ◽

Deuterium Isotope Effects

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Primary deuterium isotope effects in oxidations of benzyl-.alpha.-d alcohol by transition elements and related reagents: mechanisms of electron transfer

The Journal of Organic Chemistry ◽

10.1021/jo01315a044 ◽

1979 ◽

Vol 44 (1) ◽

pp. 162-164 ◽

Cited By ~ 11

Author(s):

Harold Kwart ◽

Thomas J. George

Keyword(s):

Electron Transfer ◽

Isotope Effects ◽

Transition Elements ◽

Deuterium Isotope Effects

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ChemInform Abstract: PRIMARY DEUTERIUM ISOTOPE EFFECTS IN OXIDATIONS OF BENZYL-α-D ALCOHOL BY TRANSITION ELEMENTS AND RELATED REAGENTS: MECHANISMS OF ELECTRON TRANSFER

Chemischer Informationsdienst ◽

10.1002/chin.197922077 ◽

1979 ◽

Vol 10 (22) ◽

Author(s):

H. KWART ◽

T. J. GEORGE

Keyword(s):

Electron Transfer ◽

Isotope Effects ◽

Transition Elements ◽

Deuterium Isotope Effects

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Determination of various hydrogen-deuterium isotope effects in carbanion reactions using electron transfer as a reference reaction

Journal of the American Chemical Society ◽

10.1021/ja00748a069 ◽

1971 ◽

Vol 93 (19) ◽

pp. 4947-4948 ◽

Cited By ~ 2

Author(s):

Robert D. Guthrie ◽

A. T. Young ◽

G. W. Pendygraft

Keyword(s):

Electron Transfer ◽

Isotope Effects ◽

Hydrogen Deuterium ◽

Deuterium Isotope Effects ◽

Reference Reaction

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Primary Deuterium Isotope Effects in the Oxidation of Benzyl-a-d Alcohol by Transition Ellements and Related Reagents: Mechanisms of Electron Transfer.

The Journal of Organic Chemistry ◽

10.1021/jo01335a607 ◽

1979 ◽

Vol 44 (21) ◽

pp. 3740-3740

Author(s):

Harold Kwart ◽

Thomas George

Keyword(s):

Electron Transfer ◽

Isotope Effects ◽

Deuterium Isotope Effects

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Deuterium isotope effects on outer-sphere electron-transfer reactions

The Journal of Physical Chemistry ◽

10.1021/j150625a011 ◽

1981 ◽

Vol 85 (25) ◽

pp. 3763-3766 ◽

Cited By ~ 24

Author(s):

Ephraim Buhks ◽

Mordechai Bixon ◽

Joshua Jortner

Keyword(s):

Electron Transfer ◽

Isotope Effects ◽

Outer Sphere ◽

Transfer Reactions ◽

Electron Transfer Reactions ◽

Deuterium Isotope Effects ◽

Outer Sphere Electron Transfer

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Mechanism of hydration and isomerisation of 4-ethylidene-2,6-di-tert-butyl-2,5-cyclohexadien-1-one. Kinetics, acid-base catalysis and solvent deuterium isotope effects

Collection of Czechoslovak Chemical Communications ◽

10.1135/cccc19790110 ◽

1979 ◽

Vol 44 (1) ◽

pp. 110-122 ◽

Cited By ~ 2

Author(s):

Jiří Velek ◽

Bohumír Koutek ◽

Milan Souček

Keyword(s):

Aqueous Medium ◽

Rate Equation ◽

Kinetic Data ◽

Isotope Effects ◽

Base Catalysis ◽

Quinone Methide ◽

Reaction Products ◽

Acid Base ◽

Deuterium Isotope Effects ◽

Hydroxybenzyl Alcohol

Competitive hydration and isomerisation of the quinone methide I at 25 °C in an aqueous medium in the region of pH 2.4-13.0 was studied spectrophotometrically. The only reaction products in the studied range of pH are 4-hydroxybenzyl alcohol (II) and 4-hydroxystyrene (III). The form of the overall rate equation corresponds to a general acid-base catalysis. The mechanism of both reactions for three markedly separated pH regions is discussed on the basis of kinetic data and solvent deuterium effect.

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