Ground spin state variability in [Fe4S4(SR)4]3-. Synthetic analogs of the reduced clusters in ferredoxins and other iron-sulfur proteins: cases of extreme sensitivity of electronic state and structure to extrinsic factors

M. J. Carney; G. C. Papaefthymiou; K. Spartalian; R. B. Frankel; Richard H. Holm

doi:10.1021/ja00226a025

Ground spin state variability in [Fe4S4(SR)4]3-. Synthetic analogs of the reduced clusters in ferredoxins and other iron-sulfur proteins: cases of extreme sensitivity of electronic state and structure to extrinsic factors

Journal of the American Chemical Society ◽

10.1021/ja00226a025 ◽

1988 ◽

Vol 110 (18) ◽

pp. 6084-6095 ◽

Cited By ~ 87

Author(s):

M. J. Carney ◽

G. C. Papaefthymiou ◽

K. Spartalian ◽

R. B. Frankel ◽

Richard H. Holm

Keyword(s):

Electronic State ◽

Spin State ◽

Extrinsic Factors ◽

Synthetic Analogs ◽

Iron Sulfur ◽

Iron Sulfur Proteins ◽

Ground Spin State ◽

Extreme Sensitivity

Download Full-text

ChemInform Abstract: Ground Spin State Variability in (Fe4S4(SR)4)3-. Synthetic Analogues of the Reduced Clusters in Ferredoxins and Other Iron-Sulfur Proteins: Cases of Extreme Sensitivity of Electronic State and Structure to Extrinsic Factors.

ChemInform ◽

10.1002/chin.198851061 ◽

1988 ◽

Vol 19 (51) ◽

Author(s):

M. J. CARNEY ◽

G. C. PAPAEFTHYMIOU ◽

K. SPARTALIAN ◽

R. B. FRANKEL ◽

R. H. HOLM

Keyword(s):

Electronic State ◽

Spin State ◽

Synthetic Analogues ◽

Extrinsic Factors ◽

Iron Sulfur ◽

Iron Sulfur Proteins ◽

Ground Spin State ◽

Extreme Sensitivity

Download Full-text

Synthetic analogs of the active sites of iron-sulfur proteins. X. Kinetics and mechanism of the ligand substitution reactions of arylthiols with the tetranuclear clusters [Fe4S4(SR)4]2-

Journal of the American Chemical Society ◽

10.1021/ja00836a011 ◽

1975 ◽

Vol 97 (3) ◽

pp. 528-533 ◽

Cited By ~ 37

Author(s):

Gary R. Dukes ◽

R. H. Holm

Keyword(s):

Active Sites ◽

Ligand Substitution ◽

Kinetics And Mechanism ◽

Substitution Reactions ◽

Synthetic Analogs ◽

Iron Sulfur ◽

Iron Sulfur Proteins ◽

Tetranuclear Clusters ◽

Ligand Substitution Reactions

Download Full-text

ChemInform Abstract: SYNTHETIC ANALOGS OF THE ACTIVE SITES OF IRON-SULFUR PROTEINS PART 6, SPECTRAL AND REDOX CHARACTERISTICS OF THE TETRANUCLEAR CLUSTERS (FE4S4(SR)4)(2-)

Chemischer Informationsdienst ◽

10.1002/chin.197436361 ◽

1974 ◽

Vol 5 (36) ◽

pp. no-no

Author(s):

B. V. DEPAMPHILIS ◽

B. A. AVERILL ◽

T. HERSKOVITZ ◽

L. JUN. QUE ◽

R. H. HOLM

Keyword(s):

Active Sites ◽

Synthetic Analogs ◽

Iron Sulfur ◽

Iron Sulfur Proteins ◽

Tetranuclear Clusters

Download Full-text

Synthetic analogs of the active sites of iron-sulfur proteins. II. Synthesis and structure of the tetra[mercapto-.mu.3-sulfido-iron] clusters, [Fe4S4(SR)4]2-

Journal of the American Chemical Society ◽

10.1021/ja00792a013 ◽

1973 ◽

Vol 95 (11) ◽

pp. 3523-3534 ◽

Cited By ~ 209

Author(s):

B. A. Averill ◽

T. Herskovitz ◽

R. H. Holm ◽

James A. Ibers

Keyword(s):

Active Sites ◽

Synthetic Analogs ◽

Iron Clusters ◽

Iron Sulfur ◽

Iron Sulfur Proteins

Download Full-text

ChemInform Abstract: SYNTHETIC ANALOGS OF THE ACTIVE SITES OF IRON-SULFUR PROTEINS PART 9, FORMATION AND SOME ELECTRONIC AND REACTIVITY PROPERTIES OF FE4S4 GLYCYL-L-CYSTEINYLGLYCYL OLIGOPEPTIDE COMPLEXES OBTAINED BY LIGAND SUBSTITUTION REACTIONS

Chemischer Informationsdienst ◽

10.1002/chin.197448437 ◽

1974 ◽

Vol 5 (48) ◽

pp. no-no

Author(s):

L. JUN. QUE ◽

J. R. ANGLIN ◽

M. A. BOBRIK ◽

A. DAVISON ◽

R. H. HOLM

Keyword(s):

Active Sites ◽

Ligand Substitution ◽

Substitution Reactions ◽

Synthetic Analogs ◽

Iron Sulfur ◽

Iron Sulfur Proteins ◽

Ligand Substitution Reactions

Download Full-text

ChemInform Abstract: SYNTHETIC ANALOGS OF THE ACTIVE SITES OF IRON-SULFUR PROTEINS PART 5, PROTONRESONANCE PROPERTIES OF THE TETRANUCLEAR CLUSTERS (FE4S4(SR)4)(2-), EVIDENCE FOR DOMINANT CONTACT INTERACTIONS

Chemischer Informationsdienst ◽

10.1002/chin.197424351 ◽

1974 ◽

Vol 5 (24) ◽

pp. no-no

Author(s):

R. H. HOLM ◽

W. D. PHILLIPS ◽

B. A. AVERILL ◽

J. J. MAYERLE ◽

T. HERSKOVITZ

Keyword(s):

Active Sites ◽

Contact Interactions ◽

Synthetic Analogs ◽

Iron Sulfur ◽

Iron Sulfur Proteins ◽

Tetranuclear Clusters

Download Full-text

Synthetic analogs of active sites of iron-sulfur proteins: bis (o-xylyldithiolato) ferrate (III) monoanion, a structurally unconstrained model for the rubredoxin Fe-S4 unit.

Proceedings of the National Academy of Sciences ◽

10.1073/pnas.72.8.2868 ◽

1975 ◽

Vol 72 (8) ◽

pp. 2868-2872 ◽

Cited By ~ 48

Author(s):

R. W. Lane ◽

J. A. Ibers ◽

R. B. Frankel ◽

R. H. Holm

Keyword(s):

Active Sites ◽

Synthetic Analogs ◽

Unconstrained Model ◽

Iron Sulfur ◽

Iron Sulfur Proteins

Download Full-text

ChemInform Abstract: SYNTHETIC ANALOGS OF THE ACTIVE SITES OF IRON-SULFUR PROTEINS. 14. SYNTHESIS, , PROPERTIES, AND STRUCTURES OF BIS(O-XYLYL-α,α′-DITHIOLATO)FERRATE(II,III) ANIONS, ANALOGS OF OXIDIZED AND REDUCED RUBREDOXIN SITES

Chemischer Informationsdienst ◽

10.1002/chin.197714054 ◽

1977 ◽

Vol 8 (14) ◽

pp. no-no

Author(s):

R. W. LANE ◽

J. A. IBERS ◽

R. B. FRANKEL ◽

G. C. PAPAEFTHYMIOU ◽

R. H. HOLM

Keyword(s):

Active Sites ◽

Synthetic Analogs ◽

Iron Sulfur ◽

Iron Sulfur Proteins ◽

Synthesis Properties

Download Full-text

Synthetic analogs of the active sites of iron-sulfur proteins. VI. Spectral and redox characteristics of the tetranuclear clusters [Fe4S4(SR)4]2-

Journal of the American Chemical Society ◽

10.1021/ja00820a017 ◽

1974 ◽

Vol 96 (13) ◽

pp. 4159-4167 ◽

Cited By ~ 150

Author(s):

B. V. DePamphilis ◽

B. A. Averill ◽

T. Herskovitz ◽

L. Que ◽

R. H. Holm

Keyword(s):

Active Sites ◽

Synthetic Analogs ◽

Iron Sulfur ◽

Iron Sulfur Proteins ◽

Tetranuclear Clusters

Download Full-text

ChemInform Abstract: Synthetic Analogs of Iron-Sulfur Proteins and Their Properties

ChemInform ◽

10.1002/chin.198735383 ◽

1987 ◽

Vol 18 (35) ◽

Author(s):

Y. OKUNO

Keyword(s):

Synthetic Analogs ◽

Iron Sulfur ◽

Iron Sulfur Proteins

Download Full-text