Resolution of the paradox of ammonia and hydroxylamine as substrate analogs for the water-oxidation reaction catalyzed by photosystem II

1988 ◽  
Vol 110 (5) ◽  
pp. 1517-1523 ◽  
Author(s):  
Warren F. Beck ◽  
Gary W. Brudvig
Keyword(s):  
Photosystem Ii ◽  
Water Oxidation ◽  
Oxidation Reaction ◽  
Substrate Analogs

FTIR Microspectroscopic Analysis of the Water Oxidation Reaction in a Single Photosystem II Microcrystal

2019 ◽  
Vol 124 (1) ◽  
pp. 121-127
Author(s):  
Yuki Kato ◽  
Satoshi Haniu ◽  
Yoshiki Nakajima ◽  
Fusamichi Akita ◽  
Jian-Ren Shen ◽  
...  
Keyword(s):  
Photosystem Ii ◽  
Water Oxidation ◽  
Oxidation Reaction

scholarly journals Structure of intermediates of the water oxidation reaction in photosystem II

2019 ◽  
Vol 75 (a1) ◽  
pp. a140-a140
Author(s):  
L. Lassalle ◽  
J. Kern ◽  
M. Ibrahim ◽  
K. D. Sutherlin ◽  
I. D. Young ◽  
...  
Keyword(s):  
Photosystem Ii ◽  
Water Oxidation ◽  
Oxidation Reaction

scholarly journals Bio-Inspired Molecular Catalysts for Water Oxidation

Catalysts ◽  
2021 ◽  
Vol 11 (9) ◽  
pp. 1068
Author(s):  
Dan Xiao ◽  
Jennifer Gregg ◽  
K. V. Lakshmi ◽  
Peter J. Bonitatibus
Keyword(s):  
Photosystem Ii ◽  
Water Oxidation ◽  
Oxidation Reaction ◽  
Energy Production ◽  
Photosynthetic Reaction Center ◽  
Transition Metal Catalysts ◽  
Environmentally Benign ◽  
Oxygen Evolving Complex ◽  
Molecular Catalysts ◽  
Oxygen Evolving

The catalytic tetranuclear manganese-calcium-oxo cluster in the photosynthetic reaction center, photosystem II, provides an excellent blueprint for light-driven water oxidation in nature. The water oxidation reaction has attracted intense interest due to its potential as a renewable, clean, and environmentally benign source of energy production. Inspired by the oxygen-evolving complex of photosystem II, a large of number of highly innovative synthetic bio-inspired molecular catalysts are being developed that incorporate relatively cheap and abundant metals such as Mn, Fe, Co, Ni, and Cu, as well as Ru and Ir, in their design. In this review, we briefly discuss the historic milestones that have been achieved in the development of transition metal catalysts and focus on a detailed description of recent progress in the field.

scholarly journals Functional Roles of D2-Lys317 and the Interacting Chloride Ion in the Water Oxidation Reaction of Photosystem II As Revealed by Fourier Transform Infrared Analysis

Biochemistry ◽  
2013 ◽  
Vol 52 (28) ◽  
pp. 4748-4757 ◽  
Author(s):  
Hiroyuki Suzuki ◽  
Jianfeng Yu ◽  
Takashi Kobayashi ◽  
Hanayo Nakanishi ◽  
Peter J. Nixon ◽  
...  
Keyword(s):  
Fourier Transform ◽  
Photosystem Ii ◽  
Water Oxidation ◽  
Oxidation Reaction ◽  
Chloride Ion ◽  
Fourier Transform Infrared ◽  
Infrared Analysis ◽  
Functional Roles

scholarly journals The Mechanism of Substrate Delivery and Activation in the Solar Water Oxidation Reaction of Photosystem II

2020 ◽  
Vol 118 (3) ◽  
pp. 610a
Author(s):  
K.V. Lakshmi ◽  
Vidmantas Kalendra ◽  
Gourab Banerjee ◽  
Ipsita Ghosh ◽  
Ke Yang ◽  
...  
Keyword(s):  
Photosystem Ii ◽  
Water Oxidation ◽  
Oxidation Reaction ◽  
Solar Water ◽  
Solar Water Oxidation

Impact Of Synthesis Route on the Water Oxidation Kinetics of Hematite Photoanodes

2020 ◽  
Author(s):  
Camilo A. Mesa ◽  
Ludmilla Steier ◽  
Benjamin Moss ◽  
Laia Francàs ◽  
James E. Thorne ◽  
...  
Keyword(s):  
Oxygen Vacancy ◽  
Reaction Kinetics ◽  
Water Oxidation ◽  
Oxidation Kinetics ◽  
Oxidation Reaction ◽  
Charge Accumulation ◽  
Optical Signals ◽  
Current Voltage ◽  
Voltage Performance ◽  
Kinetics Of

<p><i>Operando</i> spectroelectrochemical analysis is used to determine the water oxidation reaction kinetics for hematite photoanodes prepared using four different synthetic procedures. Whilst these photoanodes exhibit very different current / voltage performance, their underlying water oxidation kinetics are found to be almost invariant. Lower photoanode performance was found to correlate with the observation of optical signals indicative of charge accumulation in mid-gap oxygen vacancy states, indicating these states do not contribute directly to water oxidation.</p>

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