Synthesis and characterization of a novel bimetallic .mu.-malonyl complex. The first x-ray crystal structure of alkali metal chelation by a neutral malonyl compound

1989 ◽  
Vol 111 (19) ◽  
pp. 7633-7634 ◽  
Author(s):  
Joseph M. O'Connor ◽  
Roger Uhrhammer ◽  
Arnold L. Rheingold ◽  
Donna L. Staley
1999 ◽  
Vol 54 (11) ◽  
pp. 1375-1378 ◽  
Author(s):  
Michael Becker ◽  
Martin Jansen

The synthesis of RbHCN2 was carried out by reaction of cyanamide with rubidium amide in liquid ammonia. The crystal structure has been determinedo by x-ray powder methods (orthorhombic, P21,21,21, a = 7.299(1), b = 9.435(1), c = 9.420(1) Å; Z = 8). The anion is slightly bent (174°) and exhibits two different bond lengths (C-N: 1.17, HN-C: 1.31 Å).


1995 ◽  
Vol 230 (1-2) ◽  
pp. 205-208 ◽  
Author(s):  
Terrence Nicholson ◽  
Alan Davison ◽  
Jon A. Zubieta ◽  
Qin Chen ◽  
Alun G. Jones

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