Photophysical properties of CpRe(CO)2L complexes. Distinct orbital emissions from nonequilibrated excited states in room-temperature solution

1989 ◽  
Vol 111 (17) ◽  
pp. 6602-6610 ◽  
Author(s):  
Marsha M. Glezen ◽  
Alistair J. Lees
Keyword(s):  
Excited States ◽  
Room Temperature ◽  
Photophysical Properties ◽  
Temperature Solution

Solvent Dependence of Structural Dynamics and Spin-flip Processes in 3,4,5-tri(9H-carbazole-9-yl)benzonitrile (ortho-3CzBN)

2020 ◽  
Author(s):  
Masaki Saigo ◽  
Kiyoshi Miyata ◽  
Hajime Nakanotani ◽  
Chihaya Adachi ◽  
Ken Onda
Keyword(s):  
Dft Calculations ◽  
Excited States ◽  
Structural Changes ◽  
Photophysical Properties ◽  
Delayed Fluorescence ◽  
Time Resolved ◽  
Thermally Activated Delayed Fluorescence ◽  
Thermally Activated ◽  
Solvent Dependence ◽  
Acetonitrile Solutions

We have investigated the solvent-dependence of structural changes along with intersystem crossing of a thermally activated delayed fluorescence (TADF) molecule, 3,4,5-tri(9H-carbazole-9-yl)benzonitrile (o-3CzBN), in toluene, tetrahydrofuran, and acetonitrile solutions using time-resolved infrared (TR-IR) spectroscopy and DFT calculations. We found that the geometries of the S1 and T1 states are very similar in all solvents though the photophysical properties mostly depend on the solvent. In addition, the time-dependent DFT calculations based on these geometries suggested that the thermally activated delayed fluorescence process of o-3CzBN is governed more by the higher-lying excited states than by the structural changes in the excited states.<br>

scholarly journals Room-Temperature Solution-Processed 0D/1D Bilayer Electrodes for Translucent CsPbBr3 Perovskite Photovoltaics

Nanomaterials ◽  
2021 ◽  
Vol 11 (6) ◽  
pp. 1489
Author(s):  
Bhaskar Parida ◽  
Saemon Yoon ◽  
Dong-Won Kang
Keyword(s):  
Solar Cells ◽  
Indium Tin Oxide ◽  
High Performance ◽  
Room Temperature ◽  
Low Cost ◽  
Perovskite Solar Cells ◽  
Ambient Air ◽  
Plasma Damage ◽  
Temperature Solution ◽  
Ito Nanoparticles

Materials and processing of transparent electrodes (TEs) are key factors to creating high-performance translucent perovskite solar cells. To date, sputtered indium tin oxide (ITO) has been a general option for a rear TE of translucent solar cells. However, it requires a rather high cost due to vacuum process and also typically causes plasma damage to the underlying layer. Therefore, we introduced TE based on ITO nanoparticles (ITO-NPs) by solution processing in ambient air without any heat treatment. As it reveals insufficient conductivity, Ag nanowires (Ag-NWs) are additionally coated. The ITO-NPs/Ag-NW (0D/1D) bilayer TE exhibits a better figure of merit than sputtered ITO. After constructing CsPbBr3 perovskite solar cells, the device with 0D/1D TE offers similar average visible transmission with the cells with sputtered ITO. More interestingly, the power conversion efficiency of 0D/1D TE device was 5.64%, which outperforms the cell (4.14%) made with sputtered-ITO. These impressive findings could open up a new pathway for the development of low-cost, translucent solar cells with quick processing under ambient air at room temperature.

Chapter Open for the Excited-State Intramolecular Thiol Proton Transfer in the Room-Temperature Solution

2021 ◽  
Author(s):  
Chun-Hsiang Wang ◽  
Zong-Ying Liu ◽  
Chun-Hao Huang ◽  
Chao-Tsen Chen ◽  
Fan-Yi Meng ◽  
...  
Keyword(s):  
Excited State ◽  
Proton Transfer ◽  
Room Temperature ◽  
Temperature Solution

Photophysical properties of N719 and Z907 dyes, benchmark sensitizers for dye-sensitized solar cells, at room and low temperature

2021 ◽  
Vol 23 (10) ◽  
pp. 6182-6189
Author(s):  
Dariusz M. Niedzwiedzki
Keyword(s):  
Solar Cells ◽  
Low Temperature ◽  
Optical Spectroscopy ◽  
Room Temperature ◽  
Photophysical Properties ◽  
Dye Sensitized Solar Cells ◽  
Time Resolved ◽  
Dye Sensitized ◽  
Sensitized Solar Cells

Photophysical properties of N719 and Z907, benchmark Ru-dyes used as sensitizers in dye-sensitized solar cells, were studied by static and time-resolved optical spectroscopy at room temperature and 160 K.

Ultraviolet light-emitting diode-assisted highly sensitive room temperature NO2 gas sensor for low-temperature solution-processed ZnO/TiO2 nanorods decorated with plasmonic Au nanoparticles

Nanoscale ◽  
2021 ◽  
Author(s):  
Soon-Hwan Kwon ◽  
Tae-Hyeon Kim ◽  
Sang-Min Kim ◽  
Semi Oh ◽  
Kyoung-Kook Kim
Keyword(s):  
Gas Sensors ◽  
High Performance ◽  
Room Temperature ◽  
Au Nanoparticles ◽  
Light Emitting Diode ◽  
Light Emitting ◽  
No2 Gas Sensor ◽  
Highly Sensitive ◽  
Temperature Solution ◽  
Semiconducting Metal Oxides

Nanostructured semiconducting metal oxides such as SnO2, ZnO, TiO2, and CuO have been widely used to fabricate high performance gas sensors. To improve the sensitivity and stability of gas sensors,...

scholarly journals Highly efficient organic solar cells based on a robust room-temperature solution-processed copper iodide hole transporter

Nano Energy ◽  
2015 ◽  
Vol 16 ◽  
pp. 458-469 ◽  
Author(s):  
Kui Zhao ◽  
Guy O. Ngongang Ndjawa ◽  
Lethy Krishnan Jagadamma ◽  
Abdulrahman El Labban ◽  
Hanlin Hu ◽  
...  
Keyword(s):  
Solar Cells ◽  
Organic Solar Cells ◽  
Room Temperature ◽  
Copper Iodide ◽  
Solution Processed ◽  
Highly Efficient ◽  
Temperature Solution

Facile room-temperature solution-phase synthesis of a spherical covalent organic framework for high-resolution chromatographic separation

2015 ◽  
Vol 51 (61) ◽  
pp. 12254-12257 ◽  
Author(s):  
Cheng-Xiong Yang ◽  
Chang Liu ◽  
Yi-Meng Cao ◽  
Xiu-Ping Yan
Keyword(s):  
High Resolution ◽  
Surface Area ◽  
Chromatographic Separation ◽  
Room Temperature ◽  
Solution Phase ◽  
Phase Synthesis ◽  
Covalent Organic Framework ◽  
Solution Phase Synthesis ◽  
Temperature Solution ◽  
Organic Framework

Facile room-temperature solution-phase synthesis of a spherical covalent organic framework with large surface area and good stability for high-resolution chromatographic separation.

Sign in / Sign up

Export Citation Format

Share Document