Organotransition-metal metallacarboranes. 13. Fulvalene- and polyarene-transition metal-carborane complexes as building blocks for multilevel arrays. Stepwise synthesis and structural characterization of polymetallic linked sandwiches

1989 ◽  
Vol 111 (13) ◽  
pp. 4784-4790 ◽  
Author(s):  
James H. Davis ◽  
Ekk Sinn ◽  
Russell N. Grimes
Keyword(s):  
Transition Metal ◽  
Structural Characterization ◽  
Building Blocks ◽  
Stepwise Synthesis

scholarly journals Magnetic and structural characterization of transition metal co-doped CdS nanoparticles

2011 ◽  
Vol 2 (2) ◽  
pp. 127-131 ◽  
Author(s):  
Sanjeev Kumar ◽  
Sunil Kumar ◽  
Sanyog Jain ◽  
N. K. Verma
Keyword(s):  
Transition Metal ◽  
Structural Characterization ◽  
Cds Nanoparticles ◽  
Co Doped

scholarly journals Crystallographic and structural characterization of heterometallic platinum compounds. Part II. Heterobinuclear Pt compounds with Pt⋯M (M = transition or lantanide metal) > 3.0 Å

2012 ◽  
Vol 10 (6) ◽  
pp. 1709-1759 ◽  
Author(s):  
Milan Melnik ◽  
Ondrej Sprusansky ◽  
Clive Holloway
Keyword(s):  
Transition Metal ◽  
Chlorine Atom ◽  
Structural Characterization ◽  
Platinum Compounds ◽  
Factors Affecting ◽  
Bond Lengths ◽  
Trigonal Bipyramidal ◽  
Square Planar ◽  
Independent Molecules

AbstractThis review covers almost two hundred and twenty heterobinuclear platinum compounds in which Pt⋯M separation is over 3.0 Å. The M is a transition metal (Cu, Ag, Au, Ti, V, Cr, Mo, W, Mn, Re, Fe, Ru, Os, Co, Rh, Ir, Ni and Pd). There is an example of a lanthanide, Yb and a actinide, U. The Pt atom has oxidation numbers 0, +2 and +4. The Pt coordination geometries include trigonal planar Pt(0); square planar Pt(II); trigonal bipyramidal, and pseudo octahedral Pt(IV), with the most frequent being square planar. The most common ligands for Pt are P and C donor atoms, as well as a chlorine atom. The Pt — Ag distance of 3.002(1) Å is the shortest found in this series. There are examples which contain two crystallographically independent molecules, which differ mostly by degree of distortion and even one unique example, which contains eight such molecules. These are examples of distortion isomerism. Factors affecting bond lengths and angles are discussed and some ambiguities in coordination polyhedral are outlined.

scholarly journals Synthesis and structural characterization of transition metal dithiolene derivatives containing divalent metals as counter-cations

CrystEngComm ◽  
2019 ◽  
Vol 21 (9) ◽  
pp. 1423-1432 ◽  
Author(s):  
Oscar Castillo ◽  
Esther Delgado ◽  
Diego Hernández ◽  
Elisa Hernández ◽  
Avelino Martín ◽  
...  
Keyword(s):  
Coordination Polymer ◽  
Transition Metal ◽  
Structural Characterization ◽  
Metal Cations ◽  
Magnetic Behaviour ◽  
Divalent Metal ◽  
Divalent Metals ◽  
Divalent Metal Cations ◽  
1D Coordination Polymer

Complexes containing [Fe2(SC6H2Cl2S)4]2− or [Ni(SC6H2Cl2S)2]− entities and divalent metal cations as well as an 1D-coordination polymer K/Zn have been obtained and their magnetic behaviour studied.

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