Photofragmentation via single-electron transfer: selective labilization of carbon-carbon bonds in amino alcohols with several bonds between heteroatom substituents

1989 ◽  
Vol 111 (9) ◽  
pp. 3459-3461 ◽  
Author(s):  
Xiaohong Ci ◽  
David G. Whitten
Keyword(s):  
Electron Transfer ◽  
Amino Alcohols ◽  
Single Electron ◽  
Single Electron Transfer ◽  
Carbon Carbon Bonds ◽  
Carbon Bonds

Reversal of Polarity by Catalytic SET Oxidation: Synthesis of Azabicyclo[m.n.o]alkanes via Chemoselective Reduction of Amidines

2021 ◽  
Author(s):  
Sundarababu Baskaran ◽  
Kirana D V ◽  
Kanak Kanti Das
Keyword(s):  
Electron Transfer ◽  
Stereoselective Synthesis ◽  
Single Electron ◽  
Single Electron Transfer ◽  
Catalytic Method ◽  
One Pot ◽  
Oxidative System ◽  
Oxidation Synthesis

A one-pot catalytic method has been developed for the stereoselective synthesis of cyclopropane-fused cyclic amidines using CuBr2/K2S2O8 as an efficient single electron transfer (SET) oxidative system. The generality of this...

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