Reactions of N-halo-N-methylbenzylamines with sodium methoxide-methanol and potassium tert-butoxide-tert-butyl alcohol. Effects of .beta.-carbon substituent and base-solvent system upon the imine-forming transition state

Richard A. Bartsch; Bong Rae Cho

doi:10.1021/ja00188a046

Reactions of N-halo-N-methylbenzylamines with sodium methoxide-methanol and potassium tert-butoxide-tert-butyl alcohol. Effects of .beta.-carbon substituent and base-solvent system upon the imine-forming transition state

Journal of the American Chemical Society ◽

10.1021/ja00188a046 ◽

1989 ◽

Vol 111 (6) ◽

pp. 2252-2257 ◽

Cited By ~ 4

Author(s):

Richard A. Bartsch ◽

Bong Rae Cho

Keyword(s):

Transition State ◽

Sodium Methoxide ◽

Solvent System ◽

Butyl Alcohol ◽

Tert Butyl ◽

Tert Butyl Alcohol ◽

Alcohol Effects

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ChemInform Abstract: NEUTRAL HYDROLYSIS OF P-NITROPHENYL DICHLOROACETATE IN HIGHLY AQUEOUS TERT.-BUTYL ALCOHOL, EFFECTS DUE TO SOLVENT STRUCTURAL INTEGRITY

Chemischer Informationsdienst ◽

10.1002/chin.197417135 ◽

1974 ◽

Vol 5 (17) ◽

pp. no-no

Author(s):

J. F. J. ENGBERSEN ◽

JAN B. F. N. ENGBERTS

Keyword(s):

Structural Integrity ◽

Butyl Alcohol ◽

Tert Butyl ◽

Tert Butyl Alcohol ◽

Alcohol Effects ◽

Hydrolysis Of

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Orientation of olefin-forming elimination in reactions of 2-substituted hexanes with potassium tert-butoxide-tert-butyl alcohol and sodium methoxide-methanol

Journal of the American Chemical Society ◽

10.1021/ja01034a019 ◽

1969 ◽

Vol 91 (6) ◽

pp. 1376-1382 ◽

Cited By ~ 31

Author(s):

Richard A. Bartsch ◽

Joseph F. Bunnett

Keyword(s):

Sodium Methoxide ◽

Butyl Alcohol ◽

Tert Butyl ◽

Tert Butyl Alcohol

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Formation of Zinc–Peptide Spherical Microparticles During Lyophilization from tert-Butyl Alcohol/Water Co-solvent System

Pharmaceutical Research ◽

10.1007/s11095-008-9647-7 ◽

2008 ◽

Vol 25 (12) ◽

pp. 2799-2806 ◽

Cited By ~ 4

Author(s):

Feng Qian ◽

Nina Ni ◽

Jia-Wen Chen ◽

Sridhar Desikan ◽

Vijay Naringrekar ◽

...

Keyword(s):

Solvent System ◽

Butyl Alcohol ◽

Tert Butyl ◽

Tert Butyl Alcohol ◽

Alcohol Water ◽

Spherical Microparticles

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ChemInform Abstract: PROSTAGLANDINS AND PROSTAGLANDIN INTERMEDIATES. OXIDATIVE CLEAVAGE OF OLEFINS BY OZONIZATION AND OXIDATION IN THE SOLVENT SYSTEM ACETONE-TERT-BUTYL ALCOHOL - A METHOD FOR PREPARATION OF SUBSTITUTED CYCLOPENTYLACETIC ACIDS

Chemischer Informationsdienst ◽

10.1002/chin.198249171 ◽

1982 ◽

Vol 13 (49) ◽

Author(s):

H. SCHICK ◽

H.-P. WELZEL ◽

S. SCHWARZ ◽

G. TRUCKENBRODT

Keyword(s):

Solvent System ◽

Butyl Alcohol ◽

Oxidative Cleavage ◽

Tert Butyl ◽

Tert Butyl Alcohol

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Positional and geometrical orientation in eliminations from 2-bromoalkanes induced by sodium methoxide-methanol, potassium tert-butoxide-tert-butyl alcohol, and potassium tert-butoxide-dimethyl sulfoxide

The Journal of Organic Chemistry ◽

10.1021/jo00830a017 ◽

1970 ◽

Vol 35 (5) ◽

pp. 1334-1338 ◽

Cited By ~ 5

Author(s):

Richard A. Bartsch

Keyword(s):

Dimethyl Sulfoxide ◽

Sodium Methoxide ◽

Butyl Alcohol ◽

Tert Butyl ◽

Tert Butyl Alcohol

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ChemInform Abstract: REACTION OF P-TOLYLSULFONYLMETHYL BENZENESULFONATE WITH HYDROXIDE ION IN HIGHLY AQUEOUS TERT-BUTYL ALCOHOL-WATER. AN ANALYSIS OF SOLVENT EFFECTS ON INITIAL STATE AND TRANSITION STATE

Chemischer Informationsdienst ◽

10.1002/chin.197921109 ◽

1979 ◽

Vol 10 (21) ◽

Author(s):

H. A. J. HOLTERMAN ◽

J. B. F. N. ENGBERTS

Keyword(s):

Transition State ◽

Solvent Effects ◽

Butyl Alcohol ◽

Initial State ◽

Hydroxide Ion ◽

Tert Butyl ◽

Tert Butyl Alcohol ◽

Alcohol Water

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ChemInform Abstract: MEDIUM BASICITY EFFECTS ON THE TRANSITION STATE STRUCTURE OF E2 REACTIONS. KINETIC STUDY OF THE REACTION OF 1-CHLORO-1-PHENYL-2-ARYLETHANES WITH CROWN ETHER COMPLEXED POTASSIUM TERT-BUTOXIDE IN TERT-BUTYL ALCOHOL

Chemischer Informationsdienst ◽

10.1002/chin.197741219 ◽

1977 ◽

Vol 8 (41) ◽

pp. no-no

Author(s):

S. ALUNNI ◽

E. BACIOCCHI ◽

P. PERUCCI

Keyword(s):

Crown Ether ◽

Transition State ◽

Kinetic Study ◽

Butyl Alcohol ◽

State Structure ◽

Transition State Structure ◽

Tert Butyl ◽

Tert Butyl Alcohol

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Reaction of p-tolylsulfonylmethyl benzenesulfonate with hydroxide ion in highly aqueous tert-butyl alcohol-water. An analysis of solvent effects on initial state and transition state

The Journal of Physical Chemistry ◽

10.1021/j100467a004 ◽

1979 ◽

Vol 83 (4) ◽

pp. 443-446 ◽

Cited By ~ 7

Author(s):

Herman A. J. Holterman ◽

Jan B. F. N. Engberts

Keyword(s):

Transition State ◽

Solvent Effects ◽

Butyl Alcohol ◽

Initial State ◽

Hydroxide Ion ◽

Tert Butyl ◽

Tert Butyl Alcohol ◽

Alcohol Water

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Neutral hydrolysis of p-nitrophenyl dichloroacetate in highly aqueous tert-butyl alcohol. Effects due to solvent structural integrity

Journal of the American Chemical Society ◽

10.1021/ja00811a051 ◽

1974 ◽

Vol 96 (4) ◽

pp. 1231-1233 ◽

Cited By ~ 9

Author(s):

J. F. J. Engbersen ◽

Jan B. F. N. Engberts

Keyword(s):

Structural Integrity ◽

Butyl Alcohol ◽

Tert Butyl ◽

Tert Butyl Alcohol ◽

Alcohol Effects ◽

Hydrolysis Of

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Excess partial molal heat capacities of n-tetraamylammonium bromide in water from 10 to 80.deg. and in aqueous tert-butyl alcohol solvent system at 30.deg. and the effects on the water structure

The Journal of Physical Chemistry ◽

10.1021/j100662a017 ◽

1972 ◽

Vol 76 (18) ◽

pp. 2577-2581 ◽

Cited By ~ 12

Author(s):

R. K. Mohanty ◽

S. Sunder ◽

J. C. Ahluwalia

Keyword(s):

Water Structure ◽

Solvent System ◽

Butyl Alcohol ◽

Heat Capacities ◽

Tert Butyl ◽

Tert Butyl Alcohol ◽

Alcohol Solvent ◽

Partial Molal Heat Capacities

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