Site selectivity studies on the catalyzed reaction of isotopically labeled MnRe(CO)10 with tert-butyl isocyanide. Implications for metal dimer and cluster reactions

1989 ◽  
Vol 111 (5) ◽  
pp. 1902-1903 ◽  
Author(s):  
Peter Johnston ◽  
Graham J. Hutchings ◽  
Neil J. Coville
Keyword(s):  
Tert Butyl ◽  
Site Selectivity ◽  
Selectivity Studies

Structure and Bonding in Hexa-tert-butyl-hexa-peri-hexabenzocoronene Sandwich Complexes of Ruthenium

2018 ◽  
Vol 71 (4) ◽  
pp. 222
Author(s):  
Matthias Lein
Keyword(s):  
Electronic Interaction ◽  
Polyaromatic Hydrocarbon ◽  
Electronic Effects ◽  
Aromatic System ◽  
Tert Butyl ◽  
Coordination Sites ◽  
Site Selectivity ◽  
Sterically Demanding ◽  
Close Proximity ◽  
Steric Influence

We evaluate the balance of steric and electronic effects in the site selectivity of the binding of [Rh(Me5Cp)]+ ([RhCp·]+) to the three possible coordination sites of the polyaromatic hydrocarbon (PAH) hexa-tert-butyl-hexa-peri-hexabenzocoronene (HBBC). We find that despite the close proximity of sterically demanding tert-butyl groups to the methyl groups of the Cp* ligand, the extent of steric repulsion is minor compared to electronic interaction from bond formation and that the site selectivity is best explained in terms of the electronics of the (poly) aromatic system. This is in contrast to previous investigations on similar systems with a COD ligand where steric influence has been shown to dominate selectivity.

scholarly journals Infrared multiphoton excitation of deuterated dodecanes: final product and photolonization mass spectroscopic site selectivity studies

1984 ◽  
Author(s):  
C. E. Geosling ◽  
T. J. Manuccia ◽  
J. Laukamper ◽  
A. MacRobert ◽  
D. Feldmann ◽  
...  
Keyword(s):  
Multiphoton Excitation ◽  
Site Selectivity ◽  
Selectivity Studies

Chelation-assisted transition metal-catalysed C–H chalcogenylations

2020 ◽  
Vol 7 (8) ◽  
pp. 1022-1060 ◽  
Author(s):  
Wenbo Ma ◽  
Nikolaos Kaplaneris ◽  
Xinyue Fang ◽  
Linghui Gu ◽  
Ruhuai Mei ◽  
...  
Keyword(s):  
Transition Metal ◽  
Recent Advances ◽  
Site Selectivity ◽  
Transition Metal Catalyzed ◽  
Metal Catalyzed

This review summarizes recent advances in C–S and C–Se formations via transition metal-catalyzed C–H functionalization utilizing directing groups to control the site-selectivity.

Sign in / Sign up

Export Citation Format

Share Document