Enantioselective catalysis of the triplex Diels-Alder reaction: addition of trans-.beta.-methylstyrene to 1,3-cyclohexadiene photosensitized with (-)-1,1'-bis(2,4-dicyanonaphthalene)

1990 ◽  
Vol 112 (26) ◽  
pp. 9635-9637 ◽  
Author(s):  
Ji In Kim ◽  
Gary B. Schuster
Keyword(s):  
Alder Reaction ◽  
Diels Alder ◽  
Enantioselective Catalysis ◽  
Diels Alder Reaction

Anti-Metallocene Antibodies: A New Approach to Enantioselective Catalysis of the Diels-Alder Reaction

1995 ◽  
Vol 117 (27) ◽  
pp. 7041-7047 ◽  
Author(s):  
Jari T. Yli-Kauhaluoma ◽  
Jon A. Ashley ◽  
Chih-Hung Lo ◽  
Lee Tucker ◽  
Mary M. Wolfe ◽  
...  
Keyword(s):  
Alder Reaction ◽  
Diels Alder ◽  
Enantioselective Catalysis ◽  
New Approach ◽  
Diels Alder Reaction

scholarly journals Sulfenylphosphinoferrocenes: Novel planar chiral ligands in enantioselective catalysis

2006 ◽  
Vol 78 (2) ◽  
pp. 257-265 ◽  
Author(s):  
Silvia Cabrera ◽  
Olga García Mancheño ◽  
Ramón Gómez Arrayás ◽  
Inés Alonso ◽  
Pablo Mauleón ◽  
...  
Keyword(s):  
Transition Metal ◽  
Metal Complexes ◽  
Transition Metal Complexes ◽  
Alder Reaction ◽  
Diels Alder ◽  
Chiral Ligands ◽  
Enantioselective Catalysis ◽  
Highly Efficient ◽  
Diels Alder Reaction ◽  
Allylic Substitutions

Structurally well-defined transition-metal complexes of 1-phosphino-2-sulfenylferrocene (Fesulphos ligands) act as highly efficient catalysts in a variety of mechanistically different transformations. Excellent enantioselectivities were achieved in Pd-catalyzed allylic substitutions, desymmetrization of meso-heterobicyclic alkenes by Pd-catalyzed addition of dialkylzinc reagents, Pd-catalyzed Diels-Alder reaction of cyclopentadiene with N-acryloyl oxazolidinones, and in Cu-catalyzed formal aza-Diels-Alder reaction of Danishefsky diene to N-sulfonyl aldimines.

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