Hydrogen bonding in a family of triamides: conformation-directing effects in solution versus the solid state

1990 ◽  
Vol 112 (23) ◽  
pp. 8630-8632 ◽  
Author(s):  
Gregory P. Dado ◽  
John M. Desper ◽  
Samuel H. Gellman
2012 ◽  
Vol 68 (8) ◽  
pp. m203-m205 ◽  
Author(s):  
Mario Tenne ◽  
Yvonne Unger ◽  
Thomas Strassner

The title platinum(II) complex, [Pt(C10H8BrN2)(C5H7O2)], has a bidentate cyclometallated phenylimidazolylidene ligand and an acetylacetonate spectator ligand, which form a distorted square-planar coordination environment around the PtIIcentre. In the solid state, the molecules are oriented in a parallel fashion by intermolecular hydrogen bonding and π–π and C—H...π interactions, while close Pt...Pt contacts are not observed. The structure is only the second example for this new class of compounds.


2017 ◽  
Vol 23 (22) ◽  
pp. 5173-5173
Author(s):  
Vladimir Stilinović ◽  
Gordan Horvat ◽  
Tomica Hrenar ◽  
Vinko Nemec ◽  
Dominik Cinčić

2015 ◽  
Vol 71 (10) ◽  
pp. o697-o698 ◽  
Author(s):  
Francesca A. Vaccaro ◽  
Lynn V. Koplitz ◽  
Joel T. Mague

The asymmetric unit of the title salt, C7H7N2+·BF4−, comprises two independent but nearly identical formula units. The solid-state structure comprises corrugated layers of cations and anions, formed by C—H...F hydrogen bonding, that are approximately parallel to (010). Further C—H...F hydrogen bonding consolidates the three-dimensional architecture. The sample was refined as a two-component non-merohedral twin.


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