Reactions of dimethoxycarbene and fluoromethoxycarbene with hydroxyl compounds. Absolute rate constants and the heat of formation of dimethoxycarbene

1990 ◽  
Vol 112 (5) ◽  
pp. 1920-1926 ◽  
Author(s):  
Xue Mei Du ◽  
Hong Fan ◽  
Joshua L. Goodman ◽  
Mark A. Kesselmayer ◽  
Karsten Krogh-Jespersen ◽  
...  
Keyword(s):  
Rate Constants ◽  
Heat Of Formation ◽  
Absolute Rate ◽  
Hydroxyl Compounds

ChemInform Abstract: Reactions of Dimethoxycarbene and Fluoromethoxycarbene with Hydroxyl Compounds. Absolute Rate Constants and the Heat of Formation of Dimethoxycarbene.

ChemInform ◽  
1990 ◽  
Vol 21 (24) ◽  
Author(s):  
X.-M. DU ◽  
H. FAN ◽  
J. L. GOODMAN ◽  
M. A. KESSELMAYER ◽  
K. KROGH-JESPERSEN ◽  
...  
Keyword(s):  
Rate Constants ◽  
Heat Of Formation ◽  
Absolute Rate ◽  
Hydroxyl Compounds

ChemInform Abstract: ABSOLUTE RATE CONSTANTS FOR REACTIONS OF PHENYL RADICALS

1978 ◽  
Vol 9 (20) ◽  
Author(s):  
V. MADHAVAN ◽  
R. H. SCHULER ◽  
R. W. FESSENDEN
Keyword(s):  
Rate Constants ◽  
Absolute Rate ◽  
Phenyl Radicals

Reactions of the hydroxyl radical. Part 2.—Determination of absolute rate constants

1965 ◽  
Vol 61 (0) ◽  
pp. 1417-1424 ◽  
Author(s):  
G. E. Adams ◽  
J. W. Boag ◽  
B. D. Michael
Keyword(s):  
Hydroxyl Radical ◽  
Rate Constants ◽  
Absolute Rate

Absolute Rate Constants for Hydrocarbon Autoxidation. Part XX. Oxidation of Some Organic Sulfides

1971 ◽  
Vol 49 (12) ◽  
pp. 2178-2182 ◽  
Author(s):  
J. A. Howard ◽  
S. Korcek
Keyword(s):  
Liquid Phase ◽  
Hydrogen Atom ◽  
Rate Constants ◽  
Hydrogen Atom Abstraction ◽  
Absolute Rate ◽  
Organic Sulfides

Absolute rate constants for the liquid phase autoxidation of some organic sulfides at 30 °C have been measured. The reactivities of organic sulfides towards t-butylperoxy radicals are equal to or somewhat less than the reactivities of structurally analogous ethers. The α-alkylthiylalkylperoxy radicals appear to be about 3–5 times more reactive in hydrogen atom abstraction than the α-alkoxyalkylperoxy radicals.

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