A Three-Dimensional, Three-Connected Cubic Network of the SrSi2 Topological Type in Coordination Polymer Chemistry: [Ag(hmt)](PF6).cntdot.H2O (hmt = Hexamethylenetetraamine)

1995 ◽  
Vol 117 (51) ◽  
pp. 12861-12862 ◽  
Author(s):  
Lucia Carlucci ◽  
Gianfranco Ciani ◽  
Davide M. Proserpio ◽  
Angelo Sironi
Keyword(s):  
Coordination Polymer ◽  
Three Dimensional ◽  
Topological Type ◽  
Polymer Chemistry

scholarly journals Synthesis, Structural Features, and Catalytic Activity of an Iron(II) 3D Coordination Polymer Driven by an Ether-Bridged Pyridine-Dicarboxylate

Crystals ◽  
2019 ◽  
Vol 9 (7) ◽  
pp. 369 ◽  
Author(s):  
Na Zhao ◽  
Yu Li ◽  
Jinzhong Gu ◽  
Marina V. Kirillova ◽  
Alexander M. Kirillov
Keyword(s):  
Coordination Polymer ◽  
Three Dimensional ◽  
Topological Type ◽  
Structural Features ◽  
Organic N ◽  
Catalyst Precursor ◽  
X Ray Diffraction ◽  
Hydrothermal Conditions ◽  
Oxidative Functionalization ◽  
Diffraction Structure

New iron(II) three-dimensional coordination polymer (3D CP), [Fe(µ3-Hcpna)2]n (1), was assembled under hydrothermal conditions from 5-(4’-carboxyphenoxy)nicotinic acid (H2cpna) as a trifunctional organic N,O-building block. This stable microcrystalline CP was characterized by standard methods for coordination compounds in the solid state (infrared spectroscopy, elemental analysis, thermogravimetric analysis, powder and single-crystal X-ray diffraction). Structure and topology of 1 were examined and permitted an identification of a 3,6-connected framework of the rtl topological type. In addition, compound 1 acts as effective catalyst precursor for oxidative functionalization of alkanes (propane and cyclic C5−C8 alkanes) under homogeneous catalysis conditions, namely for the oxidation of saturated hydrocarbons with H2O2/H+ system to produce ketones and alcohols, and for alkane carboxylation with CO/H2O/S2O82− system to obtain carboxylic acids. The influence of an acid promoter and substrate scope (propane and cyclic C5−C8 alkanes) were investigated.

scholarly journals Sequence-defined l-glutamamide oligomers with pendant supramolecular motifs via iterative synthesis and orthogonal post-functionalization

2020 ◽  
Vol 11 (46) ◽  
pp. 7393-7401
Author(s):  
Marcin L. Ślęczkowski ◽  
Ian Segers ◽  
Yiliu Liu ◽  
Anja R. A. Palmans
Keyword(s):  
Three Dimensional ◽  
Synthetic Polymers ◽  
Polymer Chemistry ◽  
Supramolecular Motifs ◽  
Iterative Synthesis ◽  
Post Functionalization

One of the great challenges in polymer chemistry is to achieve discrete and sequence-defined synthetic polymers that fold in defined conformations and form well-defined three-dimensional structured particles.

Hydrothermal synthesis, structure and magnetic properties of a three-dimensional cobalt(ii) – aminophenyltetrazolate coordination polymer

2014 ◽  
Vol 43 (19) ◽  
pp. 7263-7268 ◽  
Author(s):  
Tiffany M. Smith ◽  
Michael Tichenor ◽  
Yuan-Zhu Zhang ◽  
Kim R. Dunbar ◽  
Jon Zubieta
Keyword(s):  
Magnetic Properties ◽  
Magnetic Susceptibility ◽  
Hydrothermal Synthesis ◽  
Coordination Polymer ◽  
Three Dimensional ◽  
Magnetic Behavior ◽  
Ac Magnetic Susceptibility

The three-dimensional [Co3(OH)2(H2O)2(aptet)4] exhibits magnetic properties consistent with a ferrimagnetic chain with the non-compensating resultant moment of one Co(ii) per trinuclear Co(ii) subunit and ac magnetic susceptibility indicative of glassy-like magnetic behavior.

A two-dimensional CdII coordination polymer with 2,2′-(disulfanediyl)dibenzoate and 1,10-phenanthroline ligands

2014 ◽  
Vol 70 (5) ◽  
pp. 517-521
Author(s):  
Yu-Xiu Jin ◽  
Fang Yang ◽  
Li-Min Yuan ◽  
Chao-Guo Yan ◽  
Wen-Long Liu
Keyword(s):  
Coordination Polymer ◽  
Three Dimensional ◽  
Phen Ligand ◽  
Supramolecular Architecture ◽  
Two Dimensional ◽  
Asymmetric Unit ◽  
Π Interactions ◽  
Carboxylate Groups ◽  
Phenanthroline Ligand ◽  
Phenanthroline Ligands

In poly[[μ3-2,2′-(disulfanediyl)dibenzoato-κ5 O:O,O′:O′′,O′′′](1,10-phenanthroline-κ2 N,N′)cadmium(II)], [Cd(C14H8O4S2)(C12H8N2)] n , the asymmetric unit contains one CdII cation, one 2,2′-(disulfanediyl)dibenzoate anion (denoted dtdb2−) and one 1,10-phenanthroline ligand (denoted phen). Each CdII centre is seven-coordinated by five O atoms of bridging/chelating carboxylate groups from three dtdb2− ligands and by two N atoms from one phen ligand, forming a distorted pentagonal–bipyramidal geometry. The CdII cations are bridged by dtdb2− anions to give a two-dimensional (4,4) layer. The layers are stacked to generate a three-dimensional supramolecular architecture via a combination of aromatic C—H...π and π–π interactions. The thermogravimetric and luminescence properties of this compound were also investigated.

Correction to Synthesis, Structure, and H2/CO2 Adsorption in a Three-Dimensional 4-Connected Triorganotin Coordination Polymer with a sqc Topology

2014 ◽  
Vol 53 (5) ◽  
pp. 2750-2750 ◽  
Author(s):  
Vadapalli Chandrasekhar ◽  
Chandrajeet Mohapatra ◽  
Rahul Banerjee ◽  
Arijit Mallick
Keyword(s):  
Coordination Polymer ◽  
Co2 Adsorption ◽  
Three Dimensional
Sign in / Sign up

Export Citation Format

Share Document