Kinetic Solvent Effects on Hydroxylic Hydrogen Atom Abstractions Are Independent of the Nature of the Abstracting Radical. Two Extreme Tests Using Vitamin E and Phenol

Luca Valgimigli; J. T. Banks; K.U. Ingold; J. Lusztyk

doi:10.1021/ja00145a005

Kinetic Solvent Effects on Hydroxylic Hydrogen Atom Abstractions Are Independent of the Nature of the Abstracting Radical. Two Extreme Tests Using Vitamin E and Phenol

Journal of the American Chemical Society ◽

10.1021/ja00145a005 ◽

1995 ◽

Vol 117 (40) ◽

pp. 9966-9971 ◽

Cited By ~ 114

Author(s):

Luca Valgimigli ◽

J. T. Banks ◽

K.U. Ingold ◽

J. Lusztyk

Keyword(s):

Vitamin E ◽

Hydrogen Atom ◽

Solvent Effects

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Hydrogen atom spin trapping .gamma.-irradiated fluorinated alcohols. Solvent effects on coupling constants and relative radical yields

The Journal of Physical Chemistry ◽

10.1021/j100522a004 ◽

1977 ◽

Vol 81 (7) ◽

pp. 605-607 ◽

Cited By ~ 6

Author(s):

A. Campbell Ling ◽

Larry Kevan

Keyword(s):

Hydrogen Atom ◽

Solvent Effects ◽

Spin Trapping ◽

Coupling Constants ◽

Fluorinated Alcohols ◽

Gamma Irradiated

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Reaction Pathways of Alkoxyl Radicals. The Role of Solvent Effects on C–C Bond Fragmentation and Hydrogen Atom Transfer Reactions

Synlett ◽

10.1055/s-0033-1341280 ◽

2014 ◽

Vol 25 (13) ◽

pp. 1803-1816 ◽

Cited By ~ 42

Author(s):

Massimo Bietti ◽

Michela Salamone

Keyword(s):

Hydrogen Atom ◽

Solvent Effects ◽

Hydrogen Atom Transfer ◽

Transfer Reactions ◽

Reaction Pathways ◽

Atom Transfer ◽

Atom Transfer Reactions ◽

Role Of Solvent

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Abnormal Solvent Effects on Hydrogen Atom Abstraction. 2. Resolution of the Curcumin Antioxidant Controversy. The Role of Sequential Proton Loss Electron Transfer

The Journal of Organic Chemistry ◽

10.1021/jo049254j ◽

2004 ◽

Vol 69 (18) ◽

pp. 5888-5896 ◽

Cited By ~ 255

Author(s):

Grzegorz Litwinienko ◽

K. U. Ingold

Keyword(s):

Electron Transfer ◽

Hydrogen Atom ◽

Solvent Effects ◽

Hydrogen Atom Abstraction ◽

Proton Loss

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Kinetic Solvent Effects on Hydrogen Atom Abstraction from Phenol, Aniline, and Diphenylamine. The Importance of Hydrogen Bonding on Their Radical-Trapping (Antioxidant) Activities1

The Journal of Organic Chemistry ◽

10.1021/jo951244i ◽

1996 ◽

Vol 61 (4) ◽

pp. 1316-1321 ◽

Cited By ~ 64

Author(s):

Philip A. MacFaul ◽

K. U. Ingold ◽

J. Lusztyk

Keyword(s):

Hydrogen Bonding ◽

Hydrogen Atom ◽

Solvent Effects ◽

Hydrogen Atom Abstraction ◽

Radical Trapping

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Kinetic Solvent Effects on Proton and Hydrogen Atom Transfers from Phenols. Similarities and Differences

Journal of the American Chemical Society ◽

10.1021/ja0548081 ◽

2006 ◽

Vol 128 (4) ◽

pp. 1172-1182 ◽

Cited By ~ 26

Author(s):

Merete Folmer Nielsen ◽

K. U. Ingold

Keyword(s):

Hydrogen Atom ◽

Solvent Effects ◽

Similarities And Differences ◽

Hydrogen Atom Transfers

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Solvent effects on the competitive .beta.-scission and hydrogen atom abstraction reactions of the cumyloxyl radical. Resolution of a long-standing problem

Journal of the American Chemical Society ◽

10.1021/ja00055a015 ◽

1993 ◽

Vol 115 (2) ◽

pp. 466-470 ◽

Cited By ~ 158

Author(s):

D. V. Avila ◽

C. E. Brown ◽

K. U. Ingold ◽

J. Lusztyk

Keyword(s):

Hydrogen Atom ◽

Solvent Effects ◽

Hydrogen Atom Abstraction ◽

Standing Problem

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ChemInform Abstract: HYDROGEN ATOM SPIN TRAPPING Γ-IRRADIATED FLUORINATED ALCOHOLS. SOLVENT EFFECTS ON COUPLING CONSTANTS AND RELATIVE RADICAL YIELDS

Chemischer Informationsdienst ◽

10.1002/chin.197726056 ◽

1977 ◽

Vol 8 (26) ◽

pp. no-no

Author(s):

A. C. LING ◽

L. KEVAN

Keyword(s):

Hydrogen Atom ◽

Solvent Effects ◽

Spin Trapping ◽

Coupling Constants ◽

Fluorinated Alcohols

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Antiradical Power of Carotenoids and Vitamin E: Testing the Hydrogen Atom Transfer Mechanism

The Journal of Physical Chemistry B ◽

10.1021/jp808684q ◽

2008 ◽

Vol 112 (51) ◽

pp. 16945-16951 ◽

Cited By ~ 24

Author(s):

Ana Martínez ◽

Andrés Barbosa

Keyword(s):

Vitamin E ◽

Hydrogen Atom ◽

Hydrogen Atom Transfer ◽

Transfer Mechanism ◽

Atom Transfer

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Kinetic Solvent Effects on the Reactions of the Cumyloxyl Radical with Tertiary Amides. Control over the Hydrogen Atom Transfer Reactivity and Selectivity through Solvent Polarity and Hydrogen Bonding

The Journal of Organic Chemistry ◽

10.1021/jo5026767 ◽

2015 ◽

Vol 80 (2) ◽

pp. 1149-1154 ◽

Cited By ~ 15

Author(s):

Michela Salamone ◽

Livia Mangiacapra ◽

Massimo Bietti

Keyword(s):

Hydrogen Bonding ◽

Hydrogen Atom ◽

Solvent Effects ◽

Solvent Polarity ◽

Hydrogen Atom Transfer ◽

Atom Transfer ◽

Tertiary Amides

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Solvent Effects on the Intramolecular Hydrogen-Atom Transfer between Tyrosine and Benzophenone. Diverting Reaction Mechanisms in Protic and Nonprotic Media

The Journal of Physical Chemistry C ◽

10.1021/jp901740z ◽

2009 ◽

Vol 113 (27) ◽

pp. 11695-11703 ◽

Cited By ~ 10

Author(s):

Gerald Hörner ◽

Anna Lewandowska ◽

Gordon L. Hug ◽

Bronislaw Marciniak

Keyword(s):

Hydrogen Atom ◽

Solvent Effects ◽

Reaction Mechanisms ◽

Hydrogen Atom Transfer ◽

Atom Transfer ◽

Intramolecular Hydrogen

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