Reductive Cleavage of Carbon Tetrachloride in a Polar Solvent. An Example of a Dissociative Electron Transfer with Significant Attractive Interaction between the Caged Product Fragments

2000 ◽  
Vol 122 (40) ◽  
pp. 9829-9835 ◽  
Author(s):  
Laurence Pause ◽  
Marc Robert ◽  
Jean-Michel Savéant
Keyword(s):  
Electron Transfer ◽  
Carbon Tetrachloride ◽  
Polar Solvent ◽  
Reductive Cleavage ◽  
Attractive Interaction ◽  
Dissociative Electron Transfer

Reductive cleavage of carbon–chlorine bonds at catalytic and non-catalytic electrodes in 1-butyl-3-methylimidazolium tetrafluoroborate

2015 ◽  
Vol 17 (46) ◽  
pp. 31228-31236 ◽  
Author(s):  
Abdirisak A. Isse ◽  
Ludovico Scarpa ◽  
Christian Durante ◽  
Armando Gennaro
Keyword(s):  
Electron Transfer ◽  
Electrocatalytic Activity ◽  
Reductive Cleavage ◽  
Dissociative Electron Transfer ◽  
Concerted Mechanism ◽  
Good Electrocatalytic Activity

Silver shows good electrocatalytic activity for the reduction of organic chlorides only when the dissociative electron transfer follows a concerted mechanism.

scholarly journals Metal-Free Reductive Cleavage of CN and SN Bonds by Photoactivated Electron Transfer from a Neutral Organic Donor

2013 ◽  
Vol 126 (2) ◽  
pp. 484-488 ◽  
Author(s):  
Steven O'Sullivan ◽  
Eswararao Doni ◽  
Tell Tuttle ◽  
John A. Murphy
Keyword(s):  
Electron Transfer ◽  
Reductive Cleavage ◽  
Metal Free
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