p-Hydroxyphenacyl Phototriggers: The Reactive Excited State of Phosphate Photorelease

2000 ◽  
Vol 122 (38) ◽  
pp. 9346-9347 ◽  
Author(s):  
Peter G. Conrad ◽  
Richard S. Givens ◽  
Bruno Hellrung ◽  
Cheruvallil S. Rajesh ◽  
Markus Ramseier ◽  
...  
Keyword(s):  
Excited State ◽  
Reactive Excited State

Mechanically induced generation of highly reactive excited-state oxygen molecules in cluster scattering

2011 ◽  
Vol 134 (6) ◽  
pp. 064305 ◽  
Author(s):  
Tao-Nhân V. Nguyen ◽  
Qadir K. Timerghazin ◽  
Holger Vach ◽  
Gilles H. Peslherbe
Keyword(s):  
Excited State ◽  
Reactive Excited State

Resolving the primary dynamics of bacteriorhodopsin, and of a `C13C14 locked' analog, in the reactive excited state

1999 ◽  
Vol 314 (5-6) ◽  
pp. 429-434 ◽  
Author(s):  
Tong Ye ◽  
Erez Gershgoren ◽  
N. Friedman ◽  
Michael Ottolenghi ◽  
Mudi Sheves ◽  
...  
Keyword(s):  
Excited State ◽  
Reactive Excited State

Photodisproportionation of (1,5-Cyclooctadiene) copper(I) Hexafluoroacetylacetonate Induced by Metal-to-Ligand Charge Transfer Excitation

2003 ◽  
Vol 58 (7) ◽  
pp. 704-707 ◽  
Author(s):  
Horst Kunkely ◽  
Arnd Vogler
Keyword(s):  
Excited State ◽  
Charge Transfer ◽  
Quantum Yields ◽  
Long Wavelength ◽  
Ligand Charge Transfer ◽  
Elemental Copper ◽  
Charge Transfer Excitation ◽  
Reactive Excited State

The complex CuI(COD)(hfac) with COD = 1,5- cyclooctadiene and hfac = hexafluoroacetyl-acetonate shows two long-wavelength absorptions at λmax = 308 and 241 nm which are assigned to hfac intraligand (IL) and CuI →COD metal-to-ligand charge transfer (MLCT) transitions, respectively. The photolysis of CuI(COD)(hfac) in hexane leads to the release of the olefin and the subsequent disproportionation of CuI(hfac) to elemental copper and CuII(hfac)2 with the quantum yields Φ = 10−3 at λirr =313 nm and Φ = 3×10−3 at λirr = 254 nm. It is suggested that the reactive excited state is of the MLCT type.

Resolving the primary dynamics of bacteriorhodopsin, and Locked analogs in the reactive excited state.

2001 ◽  
pp. 683-685
Author(s):  
Tong Ye ◽  
Bixue Hou ◽  
Erez Gershgoren ◽  
Michael Ottolenghi ◽  
Noga Friedman ◽  
...  
Keyword(s):  
Excited State ◽  
Reactive Excited State

Resolving the primary dynamics of bacteriorhodopsin, and Locked analogs in the reactive excited state.

2000 ◽  
Author(s):  
Tong Ye ◽  
Bixue Hou ◽  
Erez Gershgoren ◽  
Michael Ottolenghl ◽  
Sanford Ruhman ◽  
...  
Keyword(s):  
Excited State ◽  
Reactive Excited State
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