Kinetics of the C6H5 + O2 Reaction at Low Temperatures

1994 ◽  
Vol 116 (21) ◽  
pp. 9571-9576 ◽  
Author(s):  
T. Yu ◽  
M. C. Lin
Keyword(s):  
1975 ◽  
Vol 6 (1) ◽  
pp. 65-75 ◽  
Author(s):  
B. Meester ◽  
M. Döner ◽  
H. Conrad

Author(s):  
Francisco Alarcón Elvira ◽  
Violeta T. Pardío Sedas ◽  
David Martínez Herrera ◽  
Rodolfo Quintana Castro ◽  
Rosa María Oliart Ros ◽  
...  

Expression of the regulatory stress rpoS gene controls the transcription of cspA genes, which are involved in survival and adaptation to low temperatures. The purpose of this study was to assess the growth kinetics of naturally occurring V. parahaemolyticus in shellstock oysters and in vitro and the cold-shock-induced expression of the rpoS and cspA gene response in vitro during postharvest refrigeration. Naturally contaminated eastern oysters (Crassostrea virginica) and pathogenic (Vp-tdh) and nonpathogenic (Vp-tlh) isolates were stored at 7 ± 1 °C for 168 h and 216 h, respectively. The regulatory stress (rpos) and cold-shock (cspA) gene expressions were determined by reverse transcription PCR. At 24 h, the (Vp-tdh) strain grew faster (p < 0.05) than the (Vp-tlh) strain in oysters (λ = 0.33, 0.39, respectively) and in vitro (λ = 0.89, 37.65, respectively), indicating a better adaptation to cold shock for the (Vp-tdh) strain in live oysters and in vitro. At 24 h, the (Vp-tdh) strain rpoS and cspA gene expressions were upregulated by 1.9 and 2.3-fold, respectively, but the (Vp-tlh) strain rpoS and cspA gene expressions were repressed and upregulated by −0.024 and 1.9-fold, respectively. The V. parahaemolyticus strains that were isolated from tropical oysters have adaptive expression changes to survive and grow at 7 °C, according to their virulence.


1983 ◽  
Vol 14 (12) ◽  
pp. 2545-2556 ◽  
Author(s):  
Chih-An Yin ◽  
M. Döner ◽  
H. Conrad

2000 ◽  
Vol 41 (7) ◽  
pp. 53-59 ◽  
Author(s):  
U. von Gunten ◽  
U. Pinkernell

The occurrence of Cryptosporidium in raw waters and bromate formation during ozonation of bromide-containing waters leads to a difficult optimisation of ozonation processes. On the one hand inactivation of Cryptosporidium requires high ozone exposures, on the other hand under these conditions bromate formation is favored. In order to overcome this problem we need information about (i) the oxidant concentrations (ozone and OH radicals) during an ozonation process, (ii) kinetics of the inactivation of Cryptosporidium, (iii) kinetics and mechanism of bromate formation, and (iv) the reactor hydraulics. The strong temperature dependence of the inactivation of Cryptosporidium which results in a higher ozone exposure (time-integrated action of ozone) at low temperatures makes it more difficult to fulfil disinfection and bromate standards at low temperatures. Underthese conditions control options for bromate formation can be applied. Depressionof pH and addition of ammonia have been selected to be the best options. For a given ozone exposure both measures lead to a reduction of bromate formation in the order of 50%.


2019 ◽  
Vol 44 (50) ◽  
pp. 27615-27625
Author(s):  
N. Thüns ◽  
B.M. Krooss ◽  
Q. Zhang ◽  
H. Stanjek

1966 ◽  
Vol 44 (20) ◽  
pp. 2435-2443 ◽  
Author(s):  
P. W. M. Jacobs ◽  
A. Russell-Jones

The infrared spectrum of hydrazine perchlorate hemihydrate (HPH) has been determined and an assignment of the absorption bands made. Invacuo, HPH will partially dehydrate even at room temperature; when heated the remainder of the half-mole of water is lost at 61 °C. The dehydrated salt melts at 138 °C and decomposition ensues. The kinetics of decomposition may be followed in the temperature range 180–280 °C. The activation energy is 36.3 kcal/mole. At low temperatures the decomposition is represented by the chemical equation[Formula: see text]but when the temperature is high enough the rate of decomposition of the ammonium perchlorate formed becomes appreciable also. Possible reaction mechanisms are discussed.


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