Formation of Pentadienal Complexes upon Protonation of Molybdenum (1-Alkylcyclopropyl)carbynes. Electronic Effects on Reductive Elimination versus .beta.-Hydrogen Elimination in Metallacyclohexenones

Mark D. Mortimer; John D. Carter; Kevin B. Kingsbury; Khalil A. Abboud; Lisa McElwee-White

doi:10.1021/ja00098a024

Formation of Pentadienal Complexes upon Protonation of Molybdenum (1-Alkylcyclopropyl)carbynes. Electronic Effects on Reductive Elimination versus .beta.-Hydrogen Elimination in Metallacyclohexenones

Journal of the American Chemical Society ◽

10.1021/ja00098a024 ◽

1994 ◽

Vol 116 (19) ◽

pp. 8629-8637 ◽

Cited By ~ 3

Author(s):

Mark D. Mortimer ◽

John D. Carter ◽

Kevin B. Kingsbury ◽

Khalil A. Abboud ◽

Lisa McElwee-White

Keyword(s):

Reductive Elimination ◽

Electronic Effects ◽

Hydrogen Elimination

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Carbon-Heteroatom Bond-Forming Reductive Elimination. Mechanism, Importance of Trapping Reagents, and Unusual Electronic Effects during Formation of Aryl Sulfides

Journal of the American Chemical Society ◽

10.1021/ja00115a033 ◽

1995 ◽

Vol 117 (10) ◽

pp. 2937-2938 ◽

Cited By ~ 96

Author(s):

David Baranano ◽

John F. Hartwig

Keyword(s):

Reductive Elimination ◽

Electronic Effects ◽

Bond Forming ◽

Elimination Mechanism ◽

Aryl Sulfides

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Electronic Effects on Reductive Elimination To Form Carbon−Carbon and Carbon−Heteroatom Bonds from Palladium(II) Complexes

Inorganic Chemistry ◽

10.1021/ic061926w ◽

2007 ◽

Vol 46 (6) ◽

pp. 1936-1947 ◽

Cited By ~ 306

Author(s):

John F. Hartwig

Keyword(s):

Reductive Elimination ◽

Electronic Effects

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Steric and electronic effects of the tertiary phosphine ligand on the dissociative reductive elimination from cis-aryldimethyl(triarylphosphine)gold(III)

Organometallics ◽

10.1021/om00123a012 ◽

1985 ◽

Vol 4 (4) ◽

pp. 684-687 ◽

Cited By ~ 46

Author(s):

Sanshiro. Komiya ◽

Akira. Shibue

Keyword(s):

Reductive Elimination ◽

Phosphine Ligand ◽

Electronic Effects ◽

Tertiary Phosphine

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β-Hydrogen Elimination and Reductive Elimination from a κ3-PPC Nickel Complex

Organometallics ◽

10.1021/acs.organomet.8b00297 ◽

2018 ◽

Vol 37 (14) ◽

pp. 2305-2318 ◽

Cited By ~ 2

Author(s):

Amanda C. Zimmerman ◽

Michael D. Fryzuk

Keyword(s):

Nickel Complex ◽

Reductive Elimination ◽

Hydrogen Elimination

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Fate of Aryl/Amido Complexes of Rhodium(III) Supported by a POCOP Pincer Ligand: C–N Reductive Elimination, β-Hydrogen Elimination, and Relevance to Catalysis

Organometallics ◽

10.1021/om500577w ◽

2014 ◽

Vol 33 (19) ◽

pp. 5254-5262 ◽

Cited By ~ 15

Author(s):

Samuel D. Timpa ◽

Christopher J. Pell ◽

Jia Zhou ◽

Oleg V. Ozerov

Keyword(s):

Reductive Elimination ◽

Pincer Ligand ◽

Amido Complexes ◽

Hydrogen Elimination

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Carbon−Sulfur Bond-Forming Reductive Elimination Involving sp-, sp2-, and sp3-Hybridized Carbon. Mechanism, Steric Effects, and Electronic Effects on Sulfide Formation

Journal of the American Chemical Society ◽

10.1021/ja981428p ◽

1998 ◽

Vol 120 (36) ◽

pp. 9205-9219 ◽

Cited By ~ 193

Author(s):

Grace Mann ◽

David Baranano ◽

John F. Hartwig ◽

Arnold L. Rheingold ◽

Ilia A. Guzei

Keyword(s):

Reductive Elimination ◽

Steric Effects ◽

Electronic Effects ◽

Bond Forming ◽

Sulfur Bond

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Oxygen- and carbon-bound ruthenium enolates: migratory insertion, reductive elimination, .beta.-hydrogen elimination, and cyclometalation reactions

Organometallics ◽

10.1021/om00055a060 ◽

1991 ◽

Vol 10 (9) ◽

pp. 3326-3344 ◽

Cited By ~ 49

Author(s):

John F. Hartwig ◽

Robert G. Bergman ◽

Richard A. Andersen

Keyword(s):

Reductive Elimination ◽

Hydrogen Elimination ◽

Migratory Insertion

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DFT modelling of a diphosphane − N-heterocyclic carbene–Rh(i) pincer complex rearrangement: a computational evaluation of the electronic effects in C–P bond activation

Dalton Transactions ◽

10.1039/c7dt04759b ◽

2018 ◽

Vol 47 (8) ◽

pp. 2662-2669 ◽

Cited By ~ 3

Author(s):

H.-L. Qin ◽

J. Leng ◽

W. Zhang ◽

E. A. B. Kantchev

Keyword(s):

Dft Calculations ◽

Bond Activation ◽

Oxidative Addition ◽

Reductive Elimination ◽

Electronic Effects ◽

Complex Rearrangement ◽

Rate Determining Step ◽

Computational Evaluation ◽

Pincer Complex ◽

Dft Modelling

DFT calculations confirmed that the rearrangement of a PCP-Rh-H pincer to a CCP-Rh-phosphane pincer occured by C–P oxidative addition (ΔG‡ = 29.5 kcal mol−1, rate-determining step), followed by P–H reductive elimination (ΔG‡ = 4.8 kcal mol−1).

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Influences on the Relative Rates for C−N Bond-Forming Reductive Elimination and β-Hydrogen Elimination of Amides. A Case Study on the Origins of Competing Reduction in the Palladium-Catalyzed Amination of Aryl Halides

Journal of the American Chemical Society ◽

10.1021/ja954121o ◽

1996 ◽

Vol 118 (15) ◽

pp. 3626-3633 ◽

Cited By ~ 130

Author(s):

John F. Hartwig ◽

Steven Richards ◽

David Barañano ◽

Frédéric Paul

Keyword(s):

Reductive Elimination ◽

Aryl Halides ◽

Bond Forming ◽

Hydrogen Elimination ◽

Palladium Catalyzed

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ChemInform Abstract: Carbon-Sulfur Bond-Forming Reductive Elimination Involving sp-, sp2-, and sp3-Hybridized Carbon. Mechanism, Steric Effects, and Electronic Effects on Sulfide Formation.

ChemInform ◽

10.1002/chin.199903089 ◽

2010 ◽

Vol 30 (3) ◽

pp. no-no

Author(s):

G. MANN ◽

D. BARANANO ◽

J. F. HARTWIG ◽

A. L. RHEINGOLD ◽

I. A. GUZEI

Keyword(s):

Reductive Elimination ◽

Steric Effects ◽

Electronic Effects ◽

Bond Forming ◽

Sulfur Bond

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