Prototypes for the Polaronic Ferromagnet. Synthesis and Characterization of High-Spin Organic Polymers

1994 ◽  
Vol 116 (18) ◽  
pp. 8152-8161 ◽  
Author(s):  
Michael M. Murray ◽  
Piotr Kaszynski ◽  
David A. Kaisaki ◽  
Wonghil Chang ◽  
Dennis A. Dougherty
Keyword(s):  
High Spin ◽  
Synthesis And Characterization ◽  
Organic Polymers

scholarly journals Synthesis and characterization of [7]triangulene

Nanoscale ◽  
2021 ◽  
Author(s):  
Shantanu Mishra ◽  
Kun Xu ◽  
Kristjan Eimre ◽  
Hartmut Komber ◽  
Ji Ma ◽  
...  
Keyword(s):  
High Spin ◽  
Ground States ◽  
Synthesis And Characterization ◽  
Spintronic Devices

Triangulene and its π-extended homologues constitute non-Kekulé polyradical frameworks with high-spin ground states, and are anticipated to be key components of organic spintronic devices. We report a combined in-solution and...

Synthesis and characterization of the azido-bound five-coordinate high-spin iron(II) “picket fence” porphyrin complex

Polyhedron ◽  
2009 ◽  
Vol 28 (5) ◽  
pp. 954-958 ◽  
Author(s):  
Ibtissem Hachem ◽  
Mohamed Salah Belkhiria ◽  
Michel Giorgi ◽  
Charles E. Schulz ◽  
Habib Nasri
Keyword(s):  
High Spin ◽  
Synthesis And Characterization ◽  
Porphyrin Complex ◽  
Picket Fence ◽  
High Spin Iron

Synthesis and Characterization of Novel Hybrid Ladderlike Polysilsesquioxanes Containing Polypropylene Moieties

2013 ◽  
Vol 845 ◽  
pp. 204-208
Author(s):  
Deock Sam Park ◽  
Tae Sung Ha ◽  
Jung Hyurk Lim ◽  
Kyung Min Kim
Keyword(s):  
Melting Temperature ◽  
Hybrid Materials ◽  
Char Yield ◽  
Synthesis And Characterization ◽  
Hydroxyl Groups ◽  
Organic Polymers ◽  
Interesting Candidate ◽  
Ft Ir

Novel ladderlike polysilsesquioxanes containing polypropylene moieties (LPS-PP) were synthesized from LPS having chloromethylphenyl groups (LPS) and polypropylene having hydroxyl groups (PP-OH). LPS-PP was characterized by FT-IR, DSC, SEM, EDX, and TGA. The obtained LPS-PP shows no melting temperature due to the disappearance of melting temperature of PP, indicating the rigidity of Si-O-Si backbone in ladderlike LPS. The char yield of LPS-PP is higher than that of PP-OH because of the silica parts of LPS. This new LPS-PP can be an interesting candidate to fabricate hybrid materials using interactions or compatibility between PP moieties of LPS and various organic polymers.

Synthesis and characterization of a family of M2+ complexes supported by a trianionic ONO3− pincer-type ligand: towards the stabilization of high-spin square-planar complexes

2015 ◽  
Vol 44 (46) ◽  
pp. 20207-20215 ◽  
Author(s):  
M. E. Pascualini ◽  
S. A. Stoian ◽  
A. Ozarowski ◽  
N. V. Di Russo ◽  
A. E. Thuijs ◽  
...  
Keyword(s):  
High Spin ◽  
Synthesis And Characterization ◽  
Square Planar ◽  
Square Planar Complexes

A trianionic pincer-type ligand stabilizes rare Fe(ii) and Co(ii) high spin, square-planar complexes.

Synthesis and Characterization of Hydrazide-Linked and Amide-Linked Organic Polymers

2016 ◽  
Vol 8 (46) ◽  
pp. 32060-32067 ◽  
Author(s):  
Zhongshan Liu ◽  
Junjie Ou ◽  
Hongwei Wang ◽  
Xin You ◽  
Mingliang Ye
Keyword(s):  
Synthesis And Characterization ◽  
Organic Polymers

scholarly journals Synthesis and Characterization of Poly(aryleneethynylene)s and Their Corresponding Platinum-Linked Polymers

2011 ◽  
Vol 3 (3) ◽  
pp. 587-597 ◽  
Author(s):  
M. I. Hossain ◽  
D. Debnath ◽  
M. Younis ◽  
M. A. Bari ◽  
M. A. J. Miah
Keyword(s):  
Oxidative Coupling ◽  
Nmr Spectra ◽  
31P Nmr ◽  
Gel Permeation Chromatography ◽  
Degree Of Polymerization ◽  
Synthesis And Characterization ◽  
Organometallic Polymers ◽  
Organic Polymers ◽  
Gel Permeation

A series of thermally stable organic polymers [poly(2,5-diethynylpyridine] (5), [poly(1,4- diethynyl benzene)] (6), [poly(2,5-dialkyl-p-phenyleneethynylene)] (7), and [poly(p,p-diethynylbiphenyl)] (8), were synthesized by the reaction between diterminal aryleneethynylene, [HCCArCCH] {Ar = C5H5N (1); Ar = C6H6 (2); Ar = C6H4(CH3)2 (3); Ar = C6H4-C6H4 (4)} and CuCl in pyridine by Hay’s oxidative coupling method. Then the organometallic polymers [Ph (PnBu3)2Pt-C≡C-(Ar-C≡C-C≡C)n-Pt((PnBu3)2Ph] {Ar = C5H5N (9); Ar = C6H6 (10); Ar = C6H4(CH3)2 (11); Ar = C6H4-C6H4 (12)}   were synthesized by the reaction of organic polymers 5, 6, 7 and 8 with metal precursor (PnBu3)2 PtPhCl in diethylisopropileamine with good yield. These metal-linked polymers were characterized by IR, 1H-NMR, 13C-NMR and 31P-NMR spectra. Finally the molecular weight of the organometallic polymers (9, 10, 11 and 12) was determined by gel permeation chromatography (GPC). It is clearly observed from GPC that the polymers were synthesized with different degree of polymerization. Keywords:  Organometallic polymers; Hay’s Oxidative coupling; GPC. © 2011 JSR Publications. ISSN: 2070-0237 (Print); 2070-0245 (Online). All rights reserved. doi: 10.3329/jsr.v3i3.7293               J. Sci. Res. 3 (3), 587-597 (2011)

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