IR Flash Kinetic Spectroscopy of C-H Bond Activation of Cyclohexane-d0 and -d12 by Cp*Rh(CO)2 in Liquid Rare Gases: Kinetics, Thermodynamics, and Unusual Isotope Effect

1994 ◽  
Vol 116 (16) ◽  
pp. 7369-7377 ◽  
Author(s):  
Richard H. Schultz ◽  
A. A. Bengali ◽  
M. J. Tauber ◽  
Bruce H. Weiller ◽  
Eric P. Wasserman ◽  
...  
Keyword(s):  
Isotope Effect ◽  
Bond Activation ◽  
Rare Gases ◽  
Kinetic Spectroscopy

Does Methane Bind to d0 (tBu3SiNH)2Zr:NSitBu3 Prior to C-H Bond Activation? An Inter vs Intramolecular Isotope Effect Study

1994 ◽  
Vol 116 (9) ◽  
pp. 4133-4134 ◽  
Author(s):  
Christopher P. Schaller ◽  
Jeffrey B. Bonanno ◽  
Peter T. Wolczanski
Keyword(s):  
Isotope Effect ◽  
Bond Activation ◽  
Effect Study

An in-depth investigation on the C–I bond activation by rollover cycloplatinated(ii) complexes bearing monodentate phosphane ligands: kinetic and kinetic isotope effect

2018 ◽  
Vol 42 (4) ◽  
pp. 2564-2573 ◽  
Author(s):  
Hamid R. Shahsavari ◽  
Reza Babadi Aghakhanpour ◽  
Masood Fereidoonnezhad
Keyword(s):  
Isotope Effect ◽  
Kinetic Isotope Effect ◽  
Bond Activation ◽  
Addition Reaction ◽  
Oxidative Addition ◽  
Kinetic Isotope ◽  
Oxidative Addition Reaction

The oxidative addition reaction of MeI reagent to some cycloplatinated(ii) complexes was performed and kinetically investigated.

The observation of nano-voids in Au thin films

1987 ◽  
Vol 45 ◽  
pp. 366-367
Author(s):  
William Krakow
Keyword(s):  
Thin Films ◽  
Melting Point ◽  
Present Author ◽  
Stacking Faults ◽  
Damage Threshold ◽  
Ionic Species ◽  
Rare Gases ◽  
Chain Defects ◽  
Vacancy Chains ◽  
Au Thin Films

It has long been known that defects such as stacking faults and voids can be quenched from various alloyed metals heated to near their melting point. Today it is common practice to irradiate samples with various ionic species of rare gases which also form voids containing solidified phases of the same atomic species, e.g. ref. 3. Equivalently, electron irradiation has been used to produce damage events, e.g. ref. 4. Generally all of the above mentioned studies have relied on diffraction contrast to observe the defects produced down to a dimension of perhaps 10 to 20Å. Also all these studies have used ions or electrons which exceeded the damage threshold for knockon events. In the case of higher resolution studies the present author has identified vacancy and interstitial type chain defects in ion irradiated Si and was able to identify both di-interstitial and di-vacancy chains running through the foil.

The isotope effect in electronic expectation values: an all-quantum study of C6H6 and C6D6

1998 ◽  
Vol 93 (5) ◽  
pp. 801-807
Author(s):  
JOACHIM SCHULTE ◽  
MICHAEL BOHM ◽  
RAFAEL RAMIREZ
Keyword(s):  
Isotope Effect ◽  
Expectation Values
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