Kinetics of chiral symmetry breaking in crystallization

1993 ◽  
Vol 115 (22) ◽  
pp. 10211-10216 ◽  
Author(s):  
Dilip K. Kondepudi ◽  
Kim L. Bullock ◽  
Jennifer A. Digits ◽  
John K. Hall ◽  
Jason M. Miller
Keyword(s):  
Symmetry Breaking ◽  
Chiral Symmetry ◽  
Chiral Symmetry Breaking ◽  
Kinetics Of

scholarly journals Spontaneous and Controlled Macroscopic Chiral Symmetry Breaking by Means of Crystallization

Symmetry ◽  
2020 ◽  
Vol 12 (11) ◽  
pp. 1796
Author(s):  
Gérard Coquerel ◽  
Marine Hoquante
Keyword(s):  
Symmetry Breaking ◽  
Chiral Symmetry ◽  
Chiral Symmetry Breaking ◽  
Operating Conditions ◽  
Temperature Cycle ◽  
Final State ◽  
Open Questions ◽  
The Impact ◽  
Kinetics Of ◽  
Influential Parameters

In this paper, macroscopic chiral symmetry breaking refers to as the process in which a mixture of enantiomers departs from 50–50 symmetry to favor one chirality, resulting in either a scalemic mixture or a pure enantiomer. In this domain, crystallization offers various possibilities, from the classical Viedma ripening or Temperature Cycle-Induced Deracemization to the famous Kondepudi experiment and then to so-called Preferential Enrichment. These processes, together with some variants, will be depicted in terms of thermodynamic pathways, departure from equilibrium and operating conditions. Influential parameters on the final state will be reviewed as well as the impact of kinetics of the R ⇔ S equilibrium in solution on chiral symmetry breaking. How one can control the outcome of symmetry breaking is examined. Several open questions are detailed and different interpretations are discussed.

scholarly journals A Possible Resolution to Troubles of SU(2) Center Vortex Detection in Smooth Lattice Configurations

Universe ◽  
2021 ◽  
Vol 7 (5) ◽  
pp. 122
Author(s):  
Rudolf Golubich ◽  
Manfried Faber
Keyword(s):  
Symmetry Breaking ◽  
Quantum Chromodynamics ◽  
Chiral Symmetry ◽  
Chiral Symmetry Breaking ◽  
Vortex Model ◽  
Center Vortex ◽  
Vortex Detection

The center vortex model of quantum-chromodynamics can explain confinement and chiral symmetry breaking. We present a possible resolution for problems of the vortex detection in smooth configurations and discuss improvements for the detection of center vortices.

scholarly journals Spontaneous chiral symmetry breaking in the massive Landau gauge: Realistic running coupling

2021 ◽  
Vol 103 (9) ◽  
Author(s):  
Marcela Peláez ◽  
Urko Reinosa ◽  
Julien Serreau ◽  
Matthieu Tissier ◽  
Nicolás Wschebor
Keyword(s):  
Symmetry Breaking ◽  
Chiral Symmetry ◽  
Chiral Symmetry Breaking ◽  
Landau Gauge ◽  
Spontaneous Chiral Symmetry Breaking ◽  
Running Coupling

1D Mn(III) Coordination Polymers Exhibiting Chiral Symmetry Breaking and Weak Ferromagnetism

2021 ◽  
Author(s):  
Aoi Hara ◽  
Sotaro Kusumoto ◽  
Yoshihiro Sekine ◽  
Jack Harrowfield ◽  
Yang Kim ◽  
...  
Keyword(s):  
Symmetry Breaking ◽  
Chiral Symmetry ◽  
Coordination Polymers ◽  
Chiral Symmetry Breaking ◽  
Weak Ferromagnetism ◽  
Chiral Ligands ◽  
One Dimensional

Mn(III) complexes with the non-chiral ligands, (E)-N-(2-((2-aminobenzylidene)amino)-2-methylpropyl)-5-X-2-hydroxybenzamide (HLX, X = H, Cl, Br, and I), crystallise as chiral conglomerates containing amide oxygen-bridged one-dimensional coordination polymers that exhibit weak ferromagnetism. The...

scholarly journals Chiral Symmetry Breaking during Crystallization: An Advection-Mediated Nonlinear Autocatalytic Process

2004 ◽  
Vol 93 (3) ◽  
Author(s):  
Julyan H. E. Cartwright ◽  
Juan Manuel García-Ruiz ◽  
Oreste Piro ◽  
C. Ignacio Sainz-Díaz ◽  
Idan Tuval
Keyword(s):  
Symmetry Breaking ◽  
Chiral Symmetry ◽  
Chiral Symmetry Breaking ◽  
Autocatalytic Process

scholarly journals Chiral symmetry breaking beyond BCS and theorem on the width of scalars

2008 ◽  
Author(s):  
P. Bicudo ◽  
George Rupp ◽  
Eef van Beveren ◽  
Pedro Bicudo ◽  
Brigitte Hiller ◽  
...  
Keyword(s):  
Symmetry Breaking ◽  
Chiral Symmetry ◽  
Chiral Symmetry Breaking
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