1,2-Asymmetric induction in reactions of nonconjugated acyclic radicals: a new model for highly selective atom-transfer reactions of alkyl-substituted radicals

1993 ◽  
Vol 115 (19) ◽  
pp. 8585-8591 ◽  
Author(s):  
Gebhard Thoma ◽  
Dennis P. Curran ◽  
Steven V. Geib ◽  
Bernd Giese ◽  
Wolfgang Damm ◽  
...  
Keyword(s):  
Asymmetric Induction ◽  
Transfer Reactions ◽  
Atom Transfer ◽  
New Model ◽  
Atom Transfer Reactions

Nonclassical oxygen atom transfer reactions of an eight-coordinate dioxomolybdenum(vi) complex

2021 ◽  
Author(s):  
Leila G. Ranis ◽  
Jacqueline Gianino ◽  
Justin M. Hoffman ◽  
Seth N. Brown
Keyword(s):  
Oxygen Atom ◽  
Transfer Reaction ◽  
Transfer Reactions ◽  
Atom Transfer ◽  
Oxygen Atom Transfer ◽  
Oxygen Atom Transfer Reactions ◽  
Atom Transfer Reactions ◽  
Oxygen Atoms

Eight-coordinate MoO2(DOPOQ)2 can donate two oxygen atoms to substrates such as phosphines in a four-electron nonclassical oxygen atom transfer reaction.

Structure of the activated complex in atom-transfer reactions

1971 ◽  
Vol 93 (11) ◽  
pp. 2819-2820 ◽  
Author(s):  
Charles Sidney Johnson ◽  
Ann B. Gooch ◽  
Robert G. Griffin ◽  
Raymond Chang
Keyword(s):  
Transfer Reactions ◽  
Atom Transfer ◽  
Atom Transfer Reactions ◽  
Activated Complex
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