A transient intermediate of the methane monooxygenase catalytic cycle containing an FeIVFeIV cluster

1993 ◽  
Vol 115 (14) ◽  
pp. 6450-6451 ◽  
Author(s):  
Sang Kyu Lee ◽  
Brian G. Fox ◽  
Wayne A. Froland ◽  
John D. Lipscomb ◽  
Eckard Munck
Keyword(s):  
Methane Monooxygenase ◽  
Catalytic Cycle ◽  
Transient Intermediate

scholarly journals Transient intermediates of the methane monooxygenase catalytic cycle.

1993 ◽  
Vol 268 (29) ◽  
pp. 21569-21577
Author(s):  
S.K. Lee ◽  
J.C. Nesheim ◽  
J.D. Lipscomb
Keyword(s):  
Methane Monooxygenase ◽  
Catalytic Cycle ◽  
Transient Intermediates

scholarly journals Reduction of Nitrobenzene to Aniline by CO/H2O in the Presence of Palladium Nanoparticles

Catalysts ◽  
2019 ◽  
Vol 9 (5) ◽  
pp. 404 ◽  
Author(s):  
Agnieszka Krogul-Sobczak ◽  
Jakub Cedrowski ◽  
Patrycja Kasperska ◽  
Grzegorz Litwinienko
Keyword(s):  
Catalytic Activity ◽  
Palladium Nanoparticles ◽  
Metallic Nanoparticles ◽  
Active Species ◽  
Catalytic Cycle ◽  
Heterocyclic Ligands ◽  
Aromatic Nitrocompounds ◽  
First Time ◽  
Transient Intermediate

The transformation of aromatic nitrocompounds into amines by CO/H2O is catalyzed by palladium(II) complexes. Recently, we have proposed that the catalytic cycle includes Pd0 as the transient intermediate and herein, for the first time, we describe the application of palladium nanoparticles (PdNPs) stabilized by monodentate N-heterocyclic ligands as nanocatalysts facilitating the reduction of Ar–NO2 into Ar–NH2 by CO/H2O. Among the series—Pd(II) complexes, PdNPs and commercial Pdblack—the highest catalytic activity was observed for PdNPs (3.0 ± 0.5 nm) stabilized by 4-Me-pyridine in the presence of 2-Cl-pyridine. The results may be helpful for mechanistic considerations on the role of metallic nanoparticles as active species in other organic processes.

Stabilization and characterization of a reactive Fe(IV)·Fe(IV) intermediate of methane monooxygenase catalytic cycle

1993 ◽  
Vol 51 (1-2) ◽  
pp. 243
Author(s):  
Sang-Kyu Lee ◽  
Brian G. Fox ◽  
Jeremy C. Nesheim ◽  
Wayne A. Froland ◽  
Eckard Münck ◽  
...  
Keyword(s):  
Methane Monooxygenase ◽  
Catalytic Cycle

Large Scale ab Initio Quantum Chemical Calculation of the Intermediates in the Soluble Methane Monooxygenase Catalytic Cycle

2000 ◽  
Vol 122 (12) ◽  
pp. 2828-2839 ◽  
Author(s):  
Barry D. Dunietz ◽  
Michael D. Beachy ◽  
Yixiang Cao ◽  
Douglas A. Whittington ◽  
Stephen J. Lippard ◽  
...  
Keyword(s):  
Ab Initio ◽  
Quantum Chemical Calculation ◽  
Quantum Chemical ◽  
Large Scale ◽  
Methane Monooxygenase ◽  
Catalytic Cycle ◽  
Chemical Calculation ◽  
Soluble Methane Monooxygenase
Sign in / Sign up

Export Citation Format

Share Document