Reaction kinetics and thermodynamics of the (.mu.2-H)2Os3(CO)10-CO system

1993 ◽  
Vol 115 (8) ◽  
pp. 3174-3181 ◽  
Author(s):  
Anthony J. Poe ◽  
Clifford N. Sampson ◽  
Richard T. Smith ◽  
Ying Zheng
Keyword(s):  
Reaction Kinetics ◽  
Kinetics And Thermodynamics

Effect of lime mud on the reaction kinetics and thermodynamics of biomass pyrolysis

2020 ◽  
Vol 310 ◽  
pp. 123475 ◽  
Author(s):  
Hui Li ◽  
Nan Zhou ◽  
Leilei Dai ◽  
Yanling Cheng ◽  
Kirk Cobb ◽  
...  
Keyword(s):  
Reaction Kinetics ◽  
Biomass Pyrolysis ◽  
Kinetics And Thermodynamics ◽  
Lime Mud

scholarly journals Exploring the mineral–water interface: reduction and reaction kinetics of single hematite (α-Fe2O3) nanoparticles

2016 ◽  
Vol 7 (2) ◽  
pp. 1408-1414 ◽  
Author(s):  
K. Shimizu ◽  
K. Tschulik ◽  
R. G. Compton
Keyword(s):  
Reaction Kinetics ◽  
Mineral Water ◽  
Reductive Dissolution ◽  
Particle Impact ◽  
Water Interface ◽  
Fe2o3 Nanoparticles ◽  
Kinetics And Thermodynamics ◽  
Interface Reduction ◽  
Kinetics Of

Here we show that particle impact chronoamperometry allows the quantitative electrochemical characterization of individual mineral nanoparticles with adequate proton concentrations. Through this approach, we extract the kinetics and thermodynamics of the reductive dissolution of single hematite (α-Fe2O3) nanoparticles.

scholarly journals Enzymolysis reaction kinetics and thermodynamics of defatted wheat germ protein with ultrasonic pretreatment

2013 ◽  
Vol 20 (6) ◽  
pp. 1408-1413 ◽  
Author(s):  
Wenjuan Qu ◽  
Haile Ma ◽  
Bin Liu ◽  
Ronghai He ◽  
Zhongli Pan ◽  
...  
Keyword(s):  
Reaction Kinetics ◽  
Wheat Germ ◽  
Ultrasonic Pretreatment ◽  
Kinetics And Thermodynamics

scholarly journals Self-Healing Material Design and Optimization for Soft Robotic Applications

2020 ◽  
Vol 2 (2) ◽  
pp. 38
Keyword(s):  
Reaction Kinetics ◽  
Polymer Network ◽  
Polymer Networks ◽  
Material Design ◽  
Alder Reaction ◽  
Self Healing ◽  
Stimuli Responsive ◽  
Kinetics And Thermodynamics ◽  
Accurate Knowledge ◽  
Robotic Applications

The Diels-Alder reaction between furan and maleimide is the most studied example of reversible covalent chemistries for creating self-healing materials. While scientific articles reporting the synthesis of new reversible polymer networks are numerous, accurate knowledge of the reaction kinetics and thermodynamics of the dynamically reversible equilibrium reaction and the structure and property development of derived stimuli-responsive materials are less widespread. The requirements for the material properties and behavior become more stringent when designing materials for dedicated applications, such as soft robotic structures. Optima need to be sought between reasonably fast reaction kinetics for fast and efficient damage healing at moderate temperatures and mechanical strength and structural stability on the other hand. Stress relaxation is desired to make materials tougher, relieving stress before defects can grow into cracks and ultimately lead to failure, while creep can’t be allowed. Recycling and reprocessing of materials are desirable from an ecological viewpoint, while the materials should also be able to withstand static and dynamic loading in a considerable range of environmental conditions. Accurate knowledge of the reaction kinetics and thermodynamics and an in-depth knowledge of structure-processing-property relations allow smart polymer network design with tailored stimuli-responsive behavior and use as self-healing materials for robotic applications.

Reaction kinetics and thermodynamics of aqueous dissolution and growth of analcime and Na-clinoptilolite at 25 degrees C

1996 ◽  
Vol 296 (2) ◽  
pp. 128-186 ◽  
Author(s):  
W. M. Murphy ◽  
R. T. Pabalan ◽  
J. D. Prikryl ◽  
C. J. Goulet
Keyword(s):  
Reaction Kinetics ◽  
Kinetics And Thermodynamics

CO2reduction: the quest for electrocatalytic materials

2017 ◽  
Vol 5 (18) ◽  
pp. 8230-8246 ◽  
Author(s):  
Bahareh Khezri ◽  
Adrian C. Fisher ◽  
Martin Pumera
Keyword(s):  
Carbon Dioxide ◽  
Reaction Kinetics ◽  
Value Added ◽  
Kinetics And Thermodynamics ◽  
Electrochemical Conversion ◽  
Wide Range ◽  
Fundamental Understanding

Electrochemical conversion of CO2has attracted attention worldwide since this process can convert carbon dioxide to a wide range of value-added chemicals. This reaction required the development of efficient electrocatalysts and fundamental understanding of the reaction kinetics and thermodynamics to overcome the current challenges.

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