Metal ion-induced self-assembly of functionalized 2,6-oligopyridines. 1. Ligand design, synthesis, and characterization

1993 ◽  
Vol 115 (7) ◽  
pp. 2793-2807 ◽  
Author(s):  
Kevin T. Potts ◽  
Kimberly A. Gheysen Raiford ◽  
Majid Keshavarz-K
Keyword(s):  
Self Assembly ◽  
Metal Ion ◽  
Ligand Design ◽  
Synthesis And Characterization ◽  
Design Synthesis

Self-Assembly of Molecular Nanoball:  Design, Synthesis, and Characterization

2006 ◽  
Vol 71 (22) ◽  
pp. 8412-8416 ◽  
Author(s):  
Sushobhan Ghosh ◽  
Partha Sarathi Mukherjee
Keyword(s):  
Self Assembly ◽  
Synthesis And Characterization ◽  
Design Synthesis

scholarly journals Macrocyclic Assembly: A Dive into the Pecking Order and Applied Aspects of Multitalented Metallomacrocycles

2014 ◽  
Vol 2014 ◽  
pp. 1-30 ◽  
Author(s):  
Ashu Chaudhary ◽  
Ekta Rawat
Keyword(s):  
Coordination Chemistry ◽  
Metal Complexes ◽  
Self Assembly ◽  
Metal Ion ◽  
Review Article ◽  
Macrocyclic Ligands ◽  
Ion Chemistry ◽  
Pecking Order ◽  
Design Synthesis ◽  
Work Done

To aid in knowledge of macrocyclic complexes and biomedical scientists, we are presenting here a review article with compilation of work done so far along in relation to macrocyclic ligands and their metal complexes. The metal ion chemistry of macrocyclic ligands has now become a major subdivision of coordination chemistry. This overview focuses on developments in design, synthesis, and self-assembly of metal-based architectures and ligands related to macrocyclic chemistry.

Controlling the fractal dimensionality in self-assembly of terpyridine modified human insulin by Fe2+ and Eu3+ to direct in vivo effects

Nanoscale ◽  
2021 ◽  
Author(s):  
Knud J Jensen ◽  
Narendra K MIshra ◽  
Mads Østergaard ◽  
Søren R Midtgaard ◽  
Niels Johan Christensen ◽  
...  
Keyword(s):  
Human Insulin ◽  
Self Assembly ◽  
Metal Ion ◽  
Fractal Dimensionality ◽  
Higher Order ◽  
Synthesis And Characterization ◽  
In Vivo Effects ◽  
Order Structures

Metal ion-induced self-assembly (SA) of proteins into higher-order structures can provide new, dynamic nano-assemblies. Here, the synthesis and characterization of a human insulin (HI) analog modified at LysB29 with the...

Self-assembly of metal-ion-responsive supramolecular coordination complexes and their photophysical properties

2017 ◽  
Vol 46 (10) ◽  
pp. 3120-3124 ◽  
Author(s):  
Zuoli He ◽  
Meng Li ◽  
Wenxiu Que ◽  
Peter J. Stang
Keyword(s):  
Self Assembly ◽  
Metal Ion ◽  
Photophysical Properties ◽  
Coordination Complexes ◽  
Synthesis And Characterization ◽  
Supramolecular Coordination ◽  
Self Assembled

Herein, we describe the synthesis and characterization of two newly self-assembled supramolecular coordination complexes (SCCs) by using the cis-{Pt(PEt3)2}2+ center and two different kinds of pyridyl-derivatized ligands.

Self-Assembly of Hydrogels From Elastin-Mimetic Block Copolymers

2002 ◽  
Vol 724 ◽  
Author(s):  
Elizabeth R. Wright ◽  
R. Andrew McMillan ◽  
Alan Cooper ◽  
Robert P. Apkarian ◽  
Vincent P. Conticello
Keyword(s):  
Block Copolymers ◽  
Self Assembly ◽  
Triblock Copolymers ◽  
Variable Temperature ◽  
Inverse Temperature ◽  
Temperature Transition ◽  
Scanning Calorimetry ◽  
Design Synthesis ◽  
Inverse Temperature Transition ◽  
Functional Biomaterials

AbstractTriblock copolymers have traditionally been synthesized with conventional organic components. However, triblock copolymers could be synthesized by the incorporation of two incompatible protein-based polymers. The polypeptides would differ in their hydrophobicity and confer unique physiochemical properties to the resultant materials. One protein-based polymer, based on a sequence of native elastin, that has been utilized in the synthesis of biomaterials is poly (Valine-Proline-Glycine-ValineGlycine) or poly(VPGVG) [1]. This polypeptide has been shown to have an inverse temperature transition that can be adjusted by non-conservative amino acid substitutions in the fourth position [2]. By combining polypeptide blocks with different inverse temperature transition values due to hydrophobicity differences, we expect to produce amphiphilic polypeptides capable of self-assembly into hydrogels. Our research examines the design, synthesis and characterization of elastin-mimetic block copolymers as functional biomaterials. The methods that are used for the characterization include variable temperature 1D and 2D High-Resolution-NMR, cryo-High Resolutions Scanning Electron Microscopy and Differential Scanning Calorimetry.

scholarly journals Design of an n-type low glass transition temperature radical polymer

2021 ◽  
Author(s):  
Teng Chi ◽  
Siddhartha Akkiraju ◽  
Zihao Liang ◽  
Ying Tan ◽  
Ho Joong Kim ◽  
...  
Keyword(s):  
Glass Transition ◽  
Transition Temperature ◽  
Glass Transition Temperature ◽  
Synthesis And Characterization ◽  
Design Synthesis

We document the design, synthesis, and characterization of the first low glass transition temperature, n-type (i.e., preferentially-reduced) radical polymer.

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