Metal carbonyl complexes with xenon and krypton: IR spectra, carbon monoxide substitution kinetics, and bond energies

1992 ◽  
Vol 114 (27) ◽  
pp. 10910-10915 ◽  
Author(s):  
Bruce H. Weiller
Keyword(s):  
Carbon Monoxide ◽  
Ir Spectra ◽  
Metal Carbonyl ◽  
Carbonyl Complexes ◽  
Bond Energies ◽  
Metal Carbonyl Complexes

Reactions of monoazadienes with metal carbonyl complexes. 17. Photochemically induced reversible carbon monoxide insertion into ruthenium-amido bonds

1993 ◽  
Vol 32 (17) ◽  
pp. 3640-3647 ◽  
Author(s):  
Olaf C. P. Beers ◽  
Jos G. P. Delis ◽  
Wilhelmus P. Mul ◽  
Kees Vrieze ◽  
Cornelis J. Elsevier ◽  
...  
Keyword(s):  
Carbon Monoxide ◽  
Metal Carbonyl ◽  
Carbonyl Complexes ◽  
Metal Carbonyl Complexes

Determination of carbon monoxide in metal carbonyl complexes

Talanta ◽  
1969 ◽  
Vol 16 (7) ◽  
pp. 875-879 ◽  
Author(s):  
A.D. Campbell ◽  
P.E. Nelson
Keyword(s):  
Carbon Monoxide ◽  
Metal Carbonyl ◽  
Carbonyl Complexes ◽  
Metal Carbonyl Complexes

Polarized FT-IR Spectra of Transition Metal Carbonyl Complexes Oriented in Nematic Liquid Crystal Solvents

1988 ◽  
Vol 42 (3) ◽  
pp. 497-503 ◽  
Author(s):  
Ian S. Butler ◽  
Jacqueline Sedman
Keyword(s):  
Liquid Crystal ◽  
Ir Spectra ◽  
Nematic Liquid Crystal ◽  
Metal Carbonyl ◽  
Carbonyl Complexes ◽  
Vibrational Assignments ◽  
Metal Carbonyl Complexes ◽  
Ft Ir ◽  
Metal Hexacarbonyls ◽  
Bending Modes

The polarized FT-IR spectra of Mn2(CO)10, M(CO)6 (M = Cr, W), and CpM′(CO)3 (Cp = η5-C5H5; M′ = Mn, Re) dissolved in a nematic liquid crystal solvent (Merck 1132 TNC) have been recorded at room temperature. Definitive vibrational assignments have been made for the CO stretching modes of the complexes on the basis of their observed polarization behavior. For Mn2(CO)10, assignments are also proposed for MnCO bending modes. The group VIB metal hexacarbonyls are shown to be tetragonally distorted in Merck 1132 TNC. Dichroic spectra were obtained for the CO stretching modes of the CpM′(CO)3 complexes with the use of both Merck 1132 TNC and Kodak X11643 liquid crystal solvents. The complexes orient perpendicularly to the long axes of the components of the Merck liquid crystal and parallel to those of the Kodak one. The dichroic spectra show that the known distortions of the Cp′ rings in these complexes are apparently accompanied by deformation of the M′(CO)3 moieties.

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