Biosynthesis of azoxy compounds. Investigations of valanimycin biosynthesis

1992 ◽  
Vol 114 (25) ◽  
pp. 10062-10064 ◽  
Author(s):  
Ronald J. Parry ◽  
Yan Li ◽  
Fwu Lin Lii
Keyword(s):  
Azoxy Compounds

Polyfluoroarenes. Part XII. Some azoxy-compounds and benzotriazoles

1970 ◽  
pp. 1519 ◽  
Author(s):  
J. M. Birchall ◽  
R. N. Haszeldine ◽  
J. E. G. Kemp
Keyword(s):  
Azoxy Compounds

scholarly journals Asymmetric organocatalytic synthesis of tertiary azomethyl alcohols: key intermediates towards azoxy compounds and α-hydroxy-β-amino esters

2017 ◽  
Vol 15 (14) ◽  
pp. 2993-3005 ◽  
Author(s):  
José A. Carmona ◽  
Gonzalo de Gonzalo ◽  
Inmaculada Serrano ◽  
Ana M. Crespo-Peña ◽  
Michal Šimek ◽  
...  
Keyword(s):  
Nucleophilic Addition ◽  
Keto Esters ◽  
Amino Esters ◽  
Azoxy Compounds

New carbohydrate based organocatalysts have been developed for the asymmetric nucleophilic addition of formaldehyde tert-butylhydrazone to α-keto esters.

THE REDUCTION OF AROMATIC NITRO COMPOUNDS MAGNESIUM AND METHYL ALCOHOL

1953 ◽  
Vol 31 (11) ◽  
pp. 1064-1077 ◽  
Author(s):  
Karl F. Keirstead
Keyword(s):  
Methyl Alcohol ◽  
Relative Proportion ◽  
Complex Mixture ◽  
Nitro Compounds ◽  
Factors Affecting ◽  
Azoxy Compounds ◽  
Aromatic Nitro Compounds ◽  
Aromatic Nitro

A study has been made of the reduction of substituted nitro compounds by magnesium in methyl alcohol. Some nitro compounds smoothly reduce to the corresponding azoxy compounds, while others yield a complex mixture of azo, azoxy, and other compounds. An investigation has been made of the various factors affecting the velocity of the reaction and the relative proportion of the products. An attempt is made to clarify the various reactions taking place.

The hydrolytic cleavage of α-acyloxy azoxy compounds

1961 ◽  
Vol 2 (21) ◽  
pp. 749-751 ◽  
Author(s):  
Jeremiah P. Freeman
Keyword(s):  
Hydrolytic Cleavage ◽  
Azoxy Compounds

Brief Communication: Shift of Organotropy of Azoxy Compounds-Replacement of Methyl With an Octyl Group2

1974 ◽  
Vol 53 (4) ◽  
pp. 1181-1185 ◽  
Author(s):  
Jerrold M. Ward ◽  
Elizabeth K. Weisburger ◽  
Timothy Benjamin ◽  
Robert A. Moss
Keyword(s):  
Azoxy Compounds

Studies of the Wallach Transformation. II. Steric Effects in Some Symmetrically Disubstituted Azoxybenzenes

1951 ◽  
Vol 4 (2) ◽  
pp. 185
Author(s):  
PH Gore ◽  
GK Hughes
Keyword(s):  
Sulphuric Acid ◽  
Important Influence ◽  
Steric Effects ◽  
Hydroxyl Group ◽  
Azoxy Compounds ◽  
Point Of Entry ◽  
Substituent Group

Study of the behaviour of symmetrical azoxy compounds in the Wallach Transformation shows the important influence of size of a substituent group ortho to the point of entry of the hydroxyl group.�The various processes known to occur in a solution of azoxybenzene in sulphuric acid are discussed.

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