Photochemical reaction of dinuclear manganese carbonyl compounds with tributyltin hydride and with silanes

1991 ◽  
Vol 113 (24) ◽  
pp. 9155-9161 ◽  
Author(s):  
Richard J. Sullivan ◽  
Theodore L. Brown
Keyword(s):  
Carbonyl Compounds ◽  
Photochemical Reaction ◽  
Tributyltin Hydride ◽  
Manganese Carbonyl

scholarly journals Binuclear Rhenium and Manganese Carbonyl Compounds Containing Hetero-Mercaptanes

2012 ◽  
Vol 25 (1) ◽  
pp. 62-70 ◽  
Author(s):  
Md Anwarul Hoque ◽  
Md Arzu Miah ◽  
Md Nurul Abser ◽  
Abul K Azad ◽  
Kamrun N Khan ◽  
...  
Keyword(s):  
Ambient Temperature ◽  
Spectral Data ◽  
1H Nmr ◽  
Metal Atom ◽  
Carbonyl Compounds ◽  
Chemical Society ◽  
Mass Spectral Data ◽  
Heterocyclic Ligands ◽  
Mass Spectral ◽  
Manganese Carbonyl

Treatment of 2-Mercaptothiazoline, 2-Mercaptobenzimidazole, 2-Mercapto-1- methylimidazole with [M2(CO)10] (M = Re and Mn) at ambient temperature in presence of decarbonylating reagent Me3NO give the complexes [Mn2(?-?2-C3H4NS2)2(CO)6] (1), [Re2(?-?2-C3H4NS2)2(CO)6] (2), [Mn2(?-?2-C7H5SN2)2(CO)6] (3), [Re2(?-?2- C7H5SN2)2(CO)6] (4), [Re2(?-?2-C4H5N2S)2(CO)6] (5) and [Re2(?1-C4H5N2SH)(CO)9] (6) respectively. All the compounds have been characterized by IR, 1H NMR and mass spectral data. The heterocyclic ligands are expected to be coordinated to two or single metal atom through the nitrogen and sulfur atoms or via only sulfur atom.DOI: http://dx.doi.org/10.3329/jbcs.v25i1.11775 Journal of Bangladesh Chemical Society, Vol. 25(1), 62-70, 2012> 

Chemical reactions in solid manganese carbonyl compounds

1971 ◽  
Vol 26 (1) ◽  
pp. 119-124 ◽  
Author(s):  
I.G. de Jong ◽  
S.C. Srinivasan ◽  
D.R. Wiles
Keyword(s):  
Chemical Reactions ◽  
Carbonyl Compounds ◽  
Manganese Carbonyl

Rhenium and manganese carbonyl compounds incorporating tridentate chelating pyrazolyl gallate ligands

1985 ◽  
Vol 63 (8) ◽  
pp. 2261-2272 ◽  
Author(s):  
Brenda M. Louie ◽  
Steven J. Rettig ◽  
Alan Storr ◽  
James Trotter
Keyword(s):  
Carbonyl Compounds ◽  
Reducing Agents ◽  
X Ray ◽  
H Nmr ◽  
Structure Determinations ◽  
Manganese Carbonyl ◽  
Rhenium Tricarbonyl ◽  
Mode Of Coordination ◽  
Selection Of

The coordinating properties of a variety of unsymmetrical uninegative tridentate chelating "pyrazolylgallate" ligands have been studied using the tricarbonyl moieties "M(CO)3", where M = Mn or Re, as acceptor species. A series of monomeric, pseudo octahedral complexes has been characterized and a fac mode of coordination established for the tridentate gallate ligands from 1H nmr, ir measurements, and X-ray structure determinations. Nitrosylation of a selection of the rhenium tricarbonyl compounds has yielded a number of cationic rhenium mononitrosyl dicarbonyl species. The reactivity of these cations towards reducing agents has been investigated.

Synthesis and complexation of the novel tridentate anionic organogallate ligands, [Me2Ga(N2C5H7)(OCH2CH2SR)]− (R = Et or Ph)

1981 ◽  
Vol 59 (9) ◽  
pp. 1331-1341 ◽  
Author(s):  
Kenneth S. Chong ◽  
Alan Storr
Keyword(s):  
Carbonyl Compounds ◽  
Coordination Mode ◽  
The Novel ◽  
Steric Factors ◽  
Manganese Carbonyl

The synthesis and complexation of the novel tridentate chelating anionic organogallate ligands [Me2Ga(N2C5H7)(OCH2CH2SR)]− (R = Et or Ph) have been investigated. A variety of octahedral molybdenum, tungsten, and manganese carbonyl compounds have been studied in which the organogallate ligand (R = Et) is in the fac coordination mode. In addition tetrahedral "Cu•PPh3" and "Ni(NO)" complexes have been characterized which display fluxional behaviour in solution. The dearth of derivatives available using the ligand where R = Ph is attributed to steric factors.

Flash photolysis studies of dinuclear manganese carbonyl compounds

1984 ◽  
Vol 23 (23) ◽  
pp. 3748-3752 ◽  
Author(s):  
Howard W. Walker ◽  
Richard S. Herrick ◽  
Robert J. Olsen ◽  
Theodore L. Brown
Keyword(s):  
Carbonyl Compounds ◽  
Flash Photolysis ◽  
Manganese Carbonyl
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