Ligand field splitting on the xenon 4d core levels in XeFx (x = 2, 4, 6) compounds from high-resolution gas-phase photoelectron spectra: the structure of XeF6

1991 ◽  
Vol 113 (24) ◽  
pp. 9125-9131 ◽  
Author(s):  
J. N. Cutler ◽  
G. M. Bancroft ◽  
J. D. Bozek ◽  
K. H. Tan ◽  
G. J. Schrobilgen
Keyword(s):  
High Resolution ◽  
Gas Phase ◽  
Photoelectron Spectra ◽  
Ligand Field ◽  
Field Splitting

High-resolution gas phase P L-edge photoabsorption spectra of PF5

2007 ◽  
Vol 85 (10) ◽  
pp. 690-694 ◽  
Author(s):  
Y F Hu ◽  
L Zuin ◽  
R Püttner
Keyword(s):  
High Resolution ◽  
Gas Phase ◽  
Rydberg State ◽  
Rydberg States ◽  
Ligand Field ◽  
Spin Orbit ◽  
Field Splitting ◽  
Vibrational Progression ◽  
Rydberg Transitions ◽  
Franck Condon

High-resolution photoabsorption spectra of P 2s and 2p levels of PF5 are reported. Fine structure, due to spin-orbit and ligand field splittings together with strong vibrational progression, is resolved in the Rydberg region of the P 2p spectrum. A ligand field splitting of 31 meV for the 2p3/2 orbital is obtained from the fit of the Rydberg transitions. The Franck–Condon fit analysis revealed that the vibrational progression of the higher Rydberg states is different from that of the valence-Rydberg mixed 4s state. In particular, we derived a decrease in P–F bond distances of 12 and 28 pm for the 4s valence-Rydberg mixed state and the high nl Rydberg states, respectively. The natural linewidths of the P 2p levels were determined to be 55 meV.Key words: PF5, Rydberg state, vibrational, ligand field splitting, photoabsorption.

High-resolution gas-phase photoelectron spectra using synchrotron radiation: Xe 4dlinewidths and the 4d5/2:4d3/2branching ratio

1985 ◽  
Vol 31 (3) ◽  
pp. 1529-1534 ◽  
Author(s):  
B. W. Yates ◽  
K. H. Tan ◽  
L. L. Coatsworth ◽  
G. M. Bancroft
Keyword(s):  
High Resolution ◽  
Synchrotron Radiation ◽  
Gas Phase ◽  
Photoelectron Spectra

High Resolution Gas Phase Photoelectron Spectra of CoredLevels Using He II Radiation

1977 ◽  
Vol 16 (5-6) ◽  
pp. 217-220 ◽  
Author(s):  
G M Bancroft ◽  
L L Coatsworth ◽  
D K Creber ◽  
J Tse
Keyword(s):  
High Resolution ◽  
Gas Phase ◽  
Photoelectron Spectra
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