Relative rates of hydrogen atom (H.cntdot.) transfer from transition-metal hydrides to trityl radicals

1991 ◽  
Vol 113 (13) ◽  
pp. 4888-4895 ◽  
Author(s):  
David C. Eisenberg ◽  
Christophe J. C. Lawrie ◽  
Anne E. Moody ◽  
Jack R. Norton
Keyword(s):  
Hydrogen Atom ◽  
Transition Metal ◽  
Metal Hydrides ◽  
Transition Metal Hydrides

scholarly journals Complex transition metal hydrides: linear correlation of countercation electronegativity versus T–D bond lengths

2015 ◽  
Vol 51 (56) ◽  
pp. 11248-11251 ◽  
Author(s):  
T. D. Humphries ◽  
D. A. Sheppard ◽  
C. E. Buckley
Keyword(s):  
Transition Metal ◽  
Bond Length ◽  
Linear Correlation ◽  
Metal Hydrides ◽  
Bond Lengths ◽  
Transition Metal Hydrides ◽  
Complex Hydrides

For homoleptic 18-electron complex hydrides, an inverse linear correlation has been established between the T–deuterium bond length and the average electronegativity of the metal countercations.

Kinetic hydricity of transition-metal hydrides toward trityl cation

1995 ◽  
Vol 14 (9) ◽  
pp. 4031-4033 ◽  
Author(s):  
Tan-Yun Cheng ◽  
R. Morris Bullock
Keyword(s):  
Transition Metal ◽  
Metal Hydrides ◽  
Transition Metal Hydrides ◽  
Trityl Cation
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