Properties of 1,3-dialkylimidazolium chloride-aluminum chloride ionic liquids. 2. Phase transitions, densities, electrical conductivities, and viscosities

1984 ◽  
Vol 88 (12) ◽  
pp. 2614-2621 ◽  
Author(s):  
Armand A. Fannin ◽  
Danilo A. Floreani ◽  
Lowell A. King ◽  
John S. Landers ◽  
Bernard J. Piersma ◽  
...  
Keyword(s):  
Ionic Liquids ◽  
Phase Transitions ◽  
Aluminum Chloride ◽  
Electrical Conductivities

Electrochemical Investigation of Quaternary Ammonium/Aluminum Chloride Ionic Liquids

2004 ◽  
Vol 151 (8) ◽  
pp. A1168 ◽  
Author(s):  
K. Kim ◽  
Christopher Lang ◽  
Roger Moulton ◽  
Paul A. Kohl
Keyword(s):  
Ionic Liquids ◽  
Aluminum Chloride ◽  
Quaternary Ammonium ◽  
Electrochemical Investigation

Electrical Conductivities, Viscosities, and Densities of N-Methoxymethyl- and N-Butyl-N-methylpyrrolidinium Ionic Liquids with the Bis(fluorosulfonyl)amide Anion

2012 ◽  
Vol 57 (3) ◽  
pp. 751-755 ◽  
Author(s):  
Takashi Makino ◽  
Mitsuhiro Kanakubo ◽  
Tatsuya Umecky ◽  
Akira Suzuki ◽  
Tetsuo Nishida ◽  
...  
Keyword(s):  
Ionic Liquids ◽  
Electrical Conductivities

Anodic Hydrogen Electrode Reaction in Aluminum Chloride-1-Ethyl-3-methylimidazolium Chloride Ionic Liquids

2005 ◽  
Vol 73 (8) ◽  
pp. 644-650 ◽  
Author(s):  
Tetsuya TSUDA ◽  
Charles L. HUSSEY ◽  
Toshiyuki NOHIRA ◽  
Yoshihiro IKOMA ◽  
Kasumi YAMAUCHI ◽  
...  
Keyword(s):  
Ionic Liquids ◽  
Aluminum Chloride ◽  
Electrode Reaction ◽  
Hydrogen Electrode

Correlations in the Structure and Dynamics of Ionic Liquids

2009 ◽  
Vol 62 (4) ◽  
pp. 288 ◽  
Author(s):  
Angus Gray-Weale
Keyword(s):  
Ionic Liquids ◽  
Quantum Chemical ◽  
High Performance ◽  
Room Temperature ◽  
Charged Particles ◽  
Theoretical Work ◽  
Theoretical Methods ◽  
Structure And Dynamics ◽  
Electrical Conductivities ◽  
Performance Computing

A very great deal of the experimental work on room-temperature ionic liquids was done after high-performance computing became readily available for quantum-chemical or molecular-dynamic calculations. I explore the use of modern computational methods to guide or aid laboratory work, and the importance of ‘old-fashioned’ theory, from before the age of fast computers. Debye and Hückel published the first really important theoretical work on correlations between charged particles, and the Nernst–Einstein formula is still used to understand electrical conductivities. I assess the usefulness of all these theoretical methods and ideas, and discuss the particular difficulties presented by ionic liquids.

scholarly journals Electrical Conductivities and Interactions in Binary Mixtures of Imidazolium-Based Ionic Liquids with Acetonitrile and Dimethyl Sulfoxide

2020 ◽  
Vol 71 (2) ◽  
pp. 392-402
Author(s):  
Oana Ciocirlan ◽  
Amalia Stefaniu
Keyword(s):  
Electrical Conductivity ◽  
Ionic Liquids ◽  
Dimethyl Sulfoxide ◽  
Binary Mixtures ◽  
Density Functional ◽  
Binary Systems ◽  
Density Functional Theory Calculations ◽  
Functional Theory ◽  
Electrical Conductivities ◽  
Anion Type

This paper reports experimental electrical conductivities data of eight binary systems of four ionic liquids: 1-butyl-3-methylimidazolium tetrafluoroborate, [Bmim][BF4], 1-hexyl-3-methylimidazolium tetrafluoroborate, [Hmim][BF4], 1-butyl-3-methylimidazolium hexafluorophosphate, [Bmim][PF6] and 1-butyl-2,3-dimethyl-imidazolium tetrafluoroborate, [Bmmim][BF4] with the organic solvents dimethyl sulfoxide (DMSO) and acetonitrile (ACN) at atmospheric pressure and temperatures from 298.15 to 328.15 K. It was found that conductivities in the investigated ionic liquids follow the order: [Bmim][BF4] ] [Bmim][PF6] ][Bmmim][BF4] ] [Hmim][BF4]. Experimental results demonstrate that the binary mixtures possess higher electrical conductivity compared with pure components. Electrical conductivity data were correlated using Casteel�Amis and Arrhenius equations. The molar conductivity was derived from experimental data and fitted to Walden rule. The influence of the cation structure and anion type on the conductivity was discussed, which help understanding the intermolecular interactions in the binary systems. A deeper understanding of the transport behavior of ILs is given by means of density functional theory calculations (DFT)

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